Facile Preparation of a Scandium Terminal Imido Complex Supported by a Phosphazene Ligand
文献类型：期刊论文
| 作者 | Rong, Weifeng1,2; Cheng, Jianhua1; Mou, Zehuai1,2; Xie, Hongyan1,2; Cui, Dongmei1 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2013-10-14 |
| 卷号 | 32期号:19页码:5523-5529 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/om400803q |
| 英文摘要 | The scandium bis(alkyl) complex bearing the phosphazene ligand (LSc)-Sc-1(CH2SiMe3)(2) (1) (L-1 = N(PPh2=NPh)(2)) reacted with an equimolar amount of 2,6-diisopropylaniline to afford the corresponding mixed alkyl/anilido complex (LSc)-Sc-1[NHC6H3(Pr-i)(2)](CH2SiMe3) (2). Under mild conditions (20 degrees C, 4 h or 0 degrees C, 12 h), complex 2 could be swiftly transformed to the terminal imido complex (LSc)-Sc-1=N[C6H3(Pr-i)(2)](DMAP)(2) (4) in the presence of DMAP (DMAP = 4-N,N-dimethylaminopyridine). Correspondingly, treatment of the yttrium and lutetium bis(alkyl) complexes L(2)Ln(CH2SiMe3)(2) (L-2 = N [Ph2PNC6H3(Pr-i)(2)](2); Ln = Y (7), Lu (8)) with equimolar amounts of 2,6-diisopropylaniline gave the mixed alkyl/anilido complexes L(2)Ln[NHC6H3(Pr-i)(2)](CH2SiMe3) (Ln = Y (9), Lu (10)), which, however, underwent dealkylation of the Ln CH2SiMe3 species at temperatures of 60 degrees C for 9 and 100 degrees C for 10 to afford bis(anilido) complexes L(2)Ln[NHC6H3(Pr-i)(2)](2) (Ln = Y (11), Lu (12)) as redistribution products. All these complexes have been characterized by H-1, C-13{H-1}, and P-31{H-1} NMR spectroscopy and X-ray diffraction analyses, and clear structural insight into the behavior of an imido functionality on a lanthanide metal center was provided. |
| 语种 | 英语 |
| WOS记录号 | WOS:000326122600038 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46483]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Cui, Dongmei |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Rong, Weifeng,Cheng, Jianhua,Mou, Zehuai,et al. Facile Preparation of a Scandium Terminal Imido Complex Supported by a Phosphazene Ligand[J]. ORGANOMETALLICS,2013,32(19):5523-5529. |
| APA | Rong, Weifeng,Cheng, Jianhua,Mou, Zehuai,Xie, Hongyan,&Cui, Dongmei.(2013).Facile Preparation of a Scandium Terminal Imido Complex Supported by a Phosphazene Ligand.ORGANOMETALLICS,32(19),5523-5529. |
| MLA | Rong, Weifeng,et al."Facile Preparation of a Scandium Terminal Imido Complex Supported by a Phosphazene Ligand".ORGANOMETALLICS 32.19(2013):5523-5529. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。