Effect of the added amount of organically-modified montmorillonite on the catalytic carbonization of polypropylene into cup-stacked carbon nanotubes
文献类型：期刊论文
| 作者 | Gong, Jiang1,2; Liu, Jie1; Jiang, Zhiwei1; Wen, Xin1; Chen, Xuecheng1; Mijowska, Ewa3; Wang, Yanhui1; Tang, Tao1 |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2013-06-01 |
| 卷号 | 225页码:798-808 |
| 关键词 | Cup-stacked Carbon Nanotubes Polypropylene Organically-modified Montmorillonite Nio Combined Catalysis |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2013.03.112 |
| 英文摘要 | For the first time, cup-stacked carbon nanotubes (CS-CNTs) with high quality were efficiently synthesized by a one-pot approach through the carbonization of polypropylene (PP) under the combined catalysis of organically-modified montmorillonite (OMMT)/NiO. The effects of the added amount of OMMT on the yield, morphology, microstructure, phase structure and thermal stability of carbon nanomaterials (including CS-CNTs and carbon nanofibers (CNFs)) were fully investigated by scanning electron microscope, transmission electron microscope (TEM), high-resolution TEM (HRTEM), X-ray diffraction, Raman spectroscopy and thermal gravimetric analysis. Furthermore, the effects of OMMT on the degradation products of PP and the coalescence and reconstruction of NiO nanoparticles before the growth of CS-CNTs and CNFs were analyzed by gas chromatography, gas chromatography-mass spectrometry and HRTEM. It was found that after adding a low amount of OMMT, a relatively large amount of light hydrocarbons and a small amount of aromatics were produced during the degradation of PP, which promoted the coalescence and reconstruction of NiO nanoparticles into rhombic shape. Subsequently, the reshaped NiO catalysts catalyzed the light hydrocarbons and aromatics into long, straight and smooth-surface CS-CNTs with narrow length and diameter distributions. This approach offers a new potential way to largely transform waste polymer materials into valuable CS-CNTs. (c) 2013 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000321313800092 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46531]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.West Pomeranian Univ Technol, Inst Chem & Environm Engn, PL-70322 Szczecin, Poland |
| 推荐引用方式 GB/T 7714 | Gong, Jiang,Liu, Jie,Jiang, Zhiwei,et al. Effect of the added amount of organically-modified montmorillonite on the catalytic carbonization of polypropylene into cup-stacked carbon nanotubes[J]. CHEMICAL ENGINEERING JOURNAL,2013,225:798-808. |
| APA | Gong, Jiang.,Liu, Jie.,Jiang, Zhiwei.,Wen, Xin.,Chen, Xuecheng.,...&Tang, Tao.(2013).Effect of the added amount of organically-modified montmorillonite on the catalytic carbonization of polypropylene into cup-stacked carbon nanotubes.CHEMICAL ENGINEERING JOURNAL,225,798-808. |
| MLA | Gong, Jiang,et al."Effect of the added amount of organically-modified montmorillonite on the catalytic carbonization of polypropylene into cup-stacked carbon nanotubes".CHEMICAL ENGINEERING JOURNAL 225(2013):798-808. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。