Effect of elastomer on crystalline transition and deformation behavior of isotactic polypropylene
文献类型:期刊论文
作者 | Liu, Guoming1; Zhang, Xiuqin2; Liu, Yufeng1; Li, Xiuhong3; Chen, Hongyu4; Walton, Kim5; Marchand, Gary5; Wang, Dujin1 |
刊名 | POLYMER
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出版日期 | 2013-02-18 |
卷号 | 54期号:4页码:1440-1447 |
关键词 | Isotactic Polypropylene Deformation Crystal Transition |
ISSN号 | 0032-3861 |
DOI | 10.1016/j.polymer.2013.01.012 |
英文摘要 | The structural evolution during uniaxial tensile deformation of isotactic polypropylene (iPP) and its blend with olefin block copolymer (OBC) was comparatively investigated by in-situ synchrotron X-ray scattering. Small angle X-ray scattering showed that cavitation in iPP/OBC blend took place at a smaller strain than that in neat iPP. The reorientation of the cavities in iPP/OBC occurred at a lower strain than that in iPP as well. Wide angle X-ray scattering was applied to study the crystal-mesophase transition and the orientation process. Compared to the sharp transition in neat iPP, the mesophase formation and orientation in iPP/OBC blend proceeded gradually. The mesophase content and degree of orientation of iPP matrix in iPP/OBC blend were much lower than that in neat iPP within the investigated strain range. By the combination of scattering results and morphological observations, a deformation mechanism based on strain distribution and fracture mechanics was proposed. (c) 2013 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000315064000021 |
出版者 | ELSEVIER SCI LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/46575] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhang, Xiuqin |
作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China 2.Beijing Inst Fash Technol, Sch Mat Sci & Engn, Beijing Key Lab Clothing Mat R&D & Assessment, Beijing 100029, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 4.Dow Chem China Co Ltd, Shanghai 201203, Peoples R China 5.Dow Chem Co USA, Freeport, TX 77541 USA |
推荐引用方式 GB/T 7714 | Liu, Guoming,Zhang, Xiuqin,Liu, Yufeng,et al. Effect of elastomer on crystalline transition and deformation behavior of isotactic polypropylene[J]. POLYMER,2013,54(4):1440-1447. |
APA | Liu, Guoming.,Zhang, Xiuqin.,Liu, Yufeng.,Li, Xiuhong.,Chen, Hongyu.,...&Wang, Dujin.(2013).Effect of elastomer on crystalline transition and deformation behavior of isotactic polypropylene.POLYMER,54(4),1440-1447. |
MLA | Liu, Guoming,et al."Effect of elastomer on crystalline transition and deformation behavior of isotactic polypropylene".POLYMER 54.4(2013):1440-1447. |
入库方式: OAI收割
来源:化学研究所
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