中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of elastomer on crystalline transition and deformation behavior of isotactic polypropylene

文献类型:期刊论文

作者Liu, Guoming1; Zhang, Xiuqin2; Liu, Yufeng1; Li, Xiuhong3; Chen, Hongyu4; Walton, Kim5; Marchand, Gary5; Wang, Dujin1
刊名POLYMER
出版日期2013-02-18
卷号54期号:4页码:1440-1447
关键词Isotactic Polypropylene Deformation Crystal Transition
ISSN号0032-3861
DOI10.1016/j.polymer.2013.01.012
英文摘要The structural evolution during uniaxial tensile deformation of isotactic polypropylene (iPP) and its blend with olefin block copolymer (OBC) was comparatively investigated by in-situ synchrotron X-ray scattering. Small angle X-ray scattering showed that cavitation in iPP/OBC blend took place at a smaller strain than that in neat iPP. The reorientation of the cavities in iPP/OBC occurred at a lower strain than that in iPP as well. Wide angle X-ray scattering was applied to study the crystal-mesophase transition and the orientation process. Compared to the sharp transition in neat iPP, the mesophase formation and orientation in iPP/OBC blend proceeded gradually. The mesophase content and degree of orientation of iPP matrix in iPP/OBC blend were much lower than that in neat iPP within the investigated strain range. By the combination of scattering results and morphological observations, a deformation mechanism based on strain distribution and fracture mechanics was proposed. (c) 2013 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000315064000021
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/46575]  
专题中国科学院化学研究所
通讯作者Zhang, Xiuqin
作者单位1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China
2.Beijing Inst Fash Technol, Sch Mat Sci & Engn, Beijing Key Lab Clothing Mat R&D & Assessment, Beijing 100029, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
4.Dow Chem China Co Ltd, Shanghai 201203, Peoples R China
5.Dow Chem Co USA, Freeport, TX 77541 USA
推荐引用方式
GB/T 7714
Liu, Guoming,Zhang, Xiuqin,Liu, Yufeng,et al. Effect of elastomer on crystalline transition and deformation behavior of isotactic polypropylene[J]. POLYMER,2013,54(4):1440-1447.
APA Liu, Guoming.,Zhang, Xiuqin.,Liu, Yufeng.,Li, Xiuhong.,Chen, Hongyu.,...&Wang, Dujin.(2013).Effect of elastomer on crystalline transition and deformation behavior of isotactic polypropylene.POLYMER,54(4),1440-1447.
MLA Liu, Guoming,et al."Effect of elastomer on crystalline transition and deformation behavior of isotactic polypropylene".POLYMER 54.4(2013):1440-1447.

入库方式: OAI收割

来源:化学研究所

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