Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method
文献类型：期刊论文
| 作者 | Liu Feng1,2; Wang Lu1,2; Zhang Guang-chun1,2; Zheng Jun1,2; Tang Tao1 |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| 出版日期 | 2013-06-01 |
| 卷号 | 29期号:3页码:589-595 |
| 关键词 | Long Chain Branching Polyethylene Anionic Polymerization Comb-like Polymer |
| ISSN号 | 1005-9040 |
| DOI | 10.1007/s40242-013-3104-9 |
| 英文摘要 | Comb-like polyethylene(PE) was prepared via anionic polymerization combined with "graft-onto" process. The polybutadiene(PB) backbone underwent hydroxylation at 1,2-vinyl groups to obtain a controlled number of hydroxyl groups along the main chain. After the translation of hydroxyl groups to tosyl groups, a nucleophilic substitution by living anionic PB chains was achieved. The comb PE was finally obtained by the hydrogenation of the obtained unsaturated comb polymer. Since the living anionic polymerization was used to prepare the backbones and the branch chains, molecular weight to molecular weight distribution(M-w/M(n)1.5) can be well-controlled in the final comb polymer, including the average number and length of branches. |
| 语种 | 英语 |
| WOS记录号 | WOS:000320296900035 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46693]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang Tao |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Feng,Wang Lu,Zhang Guang-chun,et al. Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2013,29(3):589-595. |
| APA | Liu Feng,Wang Lu,Zhang Guang-chun,Zheng Jun,&Tang Tao.(2013).Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,29(3),589-595. |
| MLA | Liu Feng,et al."Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 29.3(2013):589-595. |
入库方式： OAI收割
来源：化学研究所
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