Fast Response and High Sensitivity Europium Metal Organic Framework Fluorescent Probe with Chelating Terpyridine Sites for Fe3+
文献类型：期刊论文
| 作者 | Zheng, Min1; Tan, Huaqiao1; Xie, Zhigang2; Zhang, Ligong1; Jing, Xiabin2; Sun, Zaicheng1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2013-02-13 |
| 卷号 | 5期号:3页码:1078-1083 |
| 关键词 | Terpyridine Europium Metal Organic Framework Fluorescent Probe Fe3++++ Ion Fe3++++ Test Paper Open Channel |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/am302862k |
| 英文摘要 | Iron is one of the most important elements in the metabolic process for all living system. However, both its deficiency and excess from normal permissible limits can induce serious disorders. We synthesized a europium-based metal-organic framework (Eu-MOF), EuL3 (L = 4'-(4-carboxyphenyl)-2,2': 6',2 ''-terpyridine), under hydrothermal conditions, and used it as a solid luminescence sensor for Fe3+ ions. The robust EuL3 shows fast response (similar to 1 min) and high sensitivity (Stern-Volmer constant K-SV = 4.1 x 10(3) L/mol) for Fe3+ ions in aqueous solution or biological systems due to the existence of chelating terpyridine and open channels. The simple and portable test paper based on the EuL3 fluorescent sensor system provides a convenient and reliable detection of Fe3+ in every day applications. This pioneering work contributes to extend the potential application of Ln-MOFs to the biological and environmental areas. |
| 语种 | 英语 |
| WOS记录号 | WOS:000315079700081 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46737]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xie, Zhigang |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, State Key Lab Luminescence & Applicat, Changchun 130033, Jilin, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Min,Tan, Huaqiao,Xie, Zhigang,et al. Fast Response and High Sensitivity Europium Metal Organic Framework Fluorescent Probe with Chelating Terpyridine Sites for Fe3+[J]. ACS APPLIED MATERIALS & INTERFACES,2013,5(3):1078-1083. |
| APA | Zheng, Min,Tan, Huaqiao,Xie, Zhigang,Zhang, Ligong,Jing, Xiabin,&Sun, Zaicheng.(2013).Fast Response and High Sensitivity Europium Metal Organic Framework Fluorescent Probe with Chelating Terpyridine Sites for Fe3+.ACS APPLIED MATERIALS & INTERFACES,5(3),1078-1083. |
| MLA | Zheng, Min,et al."Fast Response and High Sensitivity Europium Metal Organic Framework Fluorescent Probe with Chelating Terpyridine Sites for Fe3+".ACS APPLIED MATERIALS & INTERFACES 5.3(2013):1078-1083. |
入库方式： OAI收割
来源：化学研究所
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