4-(8-Quinolyl)amino-7-nitro-2,1,3-benzoxadiazole as a new colorimetric probe for rapid and visual detection of Hg2+
文献类型：期刊论文
| 作者 | Wang, Ke1; Yang, Lixue1; Zhao, Chuan1; Ma, Huimin2 |
| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2013-03-15 |
| 卷号 | 105页码:29-33 |
| 关键词 | Colorimetric Probe Hg2++++ Visual Detection 4-(8-quinolyl)Amino-7-nitro-2 1 3-benzoxadiazole |
| ISSN号 | 1386-1425 |
| DOI | 10.1016/j.saa.2012.11.114 |
| 英文摘要 | 4-Amino-7-nitro-2,1,3-benzoxadiazole (ANBD) usually serves as a scaffold for developing fluorescent probes. In this paper, however, ANBD has been used as a chromogenic unit to design a new colorimetric probe, 4-(8-quinolyl)amino-7-nitro-2,1,3-benzoxadiazole (1), for rapid and visual detection of Hg2+. The reaction of 1 with Hg2+ in NaH2PO4-Na2HPO4 buffer (pH 7.0) containing 70% (v/v) acetonitrile forms a 1:1 complex, accompanying a red shift of the absorption maximum from 482 nm to 557 nm and a distinct color change from orange to violet. Moreover the color reaction exhibits a high selectivity and sensitivity to Hg2+ only, instead of other common metal ions. This behavior may be ascribed to the formation of a specific 1-Hg2+ complex, which is supported by H-1 NMR titration experiments. The present study is not only a supplement to the detection method of Hg2+, but also a merit to the chemistry of 4-amino-7-nitro-2,1,3-benzoxadiazole. (C) 2012 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000317545400006 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46741]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Ke |
| 作者单位 | 1.Shijiazhuang Ctr Dis Control & Prevent, Shijiazhuang 050011, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Ke,Yang, Lixue,Zhao, Chuan,et al. 4-(8-Quinolyl)amino-7-nitro-2,1,3-benzoxadiazole as a new colorimetric probe for rapid and visual detection of Hg2+[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2013,105:29-33. |
| APA | Wang, Ke,Yang, Lixue,Zhao, Chuan,&Ma, Huimin.(2013).4-(8-Quinolyl)amino-7-nitro-2,1,3-benzoxadiazole as a new colorimetric probe for rapid and visual detection of Hg2+.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,105,29-33. |
| MLA | Wang, Ke,et al."4-(8-Quinolyl)amino-7-nitro-2,1,3-benzoxadiazole as a new colorimetric probe for rapid and visual detection of Hg2+".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 105(2013):29-33. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。