中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Study on the thermal degradation behavior and flame-retardant property of polylactide/PEDPP blends

文献类型:期刊论文

作者Lin, Hai-Juan1,2; Han, Li-Jing1; Wang, Xue-Mei1,2; Bian, Yi-Jie1,2; Li, Yue-Sheng3; Dong, Li-Song1
刊名POLYMERS FOR ADVANCED TECHNOLOGIES
出版日期2013-06-01
卷号24期号:6页码:576-583
关键词Polylactide Flame Retardant Thermal Degradation Mechanism
ISSN号1042-7147
DOI10.1002/pat.3120
英文摘要A phosphorus-containing polyester, poly (ethylene diglycol phenylphosphinate) (PEDPP) was synthesized from phenylphosphonic dichloride and ethylene diglycol. The structure of PEDPP has been determined by Fourier transform infrared (FTIR) spectroscopy, 1H nuclear magnetic resonance and matrix assisted laser desorption ionization-time of flight-mass spectrometer. A series of polylactide (PLA) blends with various content of PEDPP as flame retardant was prepared by direct melt compounding; the PLA/PEDPP blend is partially miscible. PEDPP is an effective flame retardant for PLA. The limiting oxygen index values increased from 19.7% for pure PLA to 29.0% for the blend containing 10wt% PEDPP. Thermogravimetric analysis-FTIR analysis indicated that the PEDPP affected the pyrolytic decomposition process of PLA, which is established by the change of the pyrolytic decomposition rate and the gross mass of gaseous fuel formation. The pyrolytic decomposition activation energies of PLA and PLA/10%PEDPP were estimated via FlynnWallOzawa method. Copyright (c) 2013 John Wiley & Sons, Ltd.
语种英语
WOS记录号WOS:000318944900007
出版者WILEY-BLACKWELL
源URL[http://ir.iccas.ac.cn/handle/121111/46743]  
专题中国科学院化学研究所
通讯作者Dong, Li-Song
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, KLPE, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Lin, Hai-Juan,Han, Li-Jing,Wang, Xue-Mei,et al. Study on the thermal degradation behavior and flame-retardant property of polylactide/PEDPP blends[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2013,24(6):576-583.
APA Lin, Hai-Juan,Han, Li-Jing,Wang, Xue-Mei,Bian, Yi-Jie,Li, Yue-Sheng,&Dong, Li-Song.(2013).Study on the thermal degradation behavior and flame-retardant property of polylactide/PEDPP blends.POLYMERS FOR ADVANCED TECHNOLOGIES,24(6),576-583.
MLA Lin, Hai-Juan,et al."Study on the thermal degradation behavior and flame-retardant property of polylactide/PEDPP blends".POLYMERS FOR ADVANCED TECHNOLOGIES 24.6(2013):576-583.

入库方式: OAI收割

来源:化学研究所

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