Study on the thermal degradation behavior and flame-retardant property of polylactide/PEDPP blends
文献类型：期刊论文
| 作者 | Lin, Hai-Juan1,2; Han, Li-Jing1; Wang, Xue-Mei1,2; Bian, Yi-Jie1,2; Li, Yue-Sheng3; Dong, Li-Song1 |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2013-06-01 |
| 卷号 | 24期号:6页码:576-583 |
| 关键词 | Polylactide Flame Retardant Thermal Degradation Mechanism |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.3120 |
| 英文摘要 | A phosphorus-containing polyester, poly (ethylene diglycol phenylphosphinate) (PEDPP) was synthesized from phenylphosphonic dichloride and ethylene diglycol. The structure of PEDPP has been determined by Fourier transform infrared (FTIR) spectroscopy, 1H nuclear magnetic resonance and matrix assisted laser desorption ionization-time of flight-mass spectrometer. A series of polylactide (PLA) blends with various content of PEDPP as flame retardant was prepared by direct melt compounding; the PLA/PEDPP blend is partially miscible. PEDPP is an effective flame retardant for PLA. The limiting oxygen index values increased from 19.7% for pure PLA to 29.0% for the blend containing 10wt% PEDPP. Thermogravimetric analysis-FTIR analysis indicated that the PEDPP affected the pyrolytic decomposition process of PLA, which is established by the change of the pyrolytic decomposition rate and the gross mass of gaseous fuel formation. The pyrolytic decomposition activation energies of PLA and PLA/10%PEDPP were estimated via FlynnWallOzawa method. Copyright (c) 2013 John Wiley & Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000318944900007 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46743]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Dong, Li-Song |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, KLPE, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, Hai-Juan,Han, Li-Jing,Wang, Xue-Mei,et al. Study on the thermal degradation behavior and flame-retardant property of polylactide/PEDPP blends[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2013,24(6):576-583. |
| APA | Lin, Hai-Juan,Han, Li-Jing,Wang, Xue-Mei,Bian, Yi-Jie,Li, Yue-Sheng,&Dong, Li-Song.(2013).Study on the thermal degradation behavior and flame-retardant property of polylactide/PEDPP blends.POLYMERS FOR ADVANCED TECHNOLOGIES,24(6),576-583. |
| MLA | Lin, Hai-Juan,et al."Study on the thermal degradation behavior and flame-retardant property of polylactide/PEDPP blends".POLYMERS FOR ADVANCED TECHNOLOGIES 24.6(2013):576-583. |
入库方式： OAI收割
来源：化学研究所
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