Construction of Planar and Bulk Integrated Heterojunction Polymer Solar Cells Using Cross-Linkable D-A Copolymer
文献类型：期刊论文
| 作者 | Xu, Qi1; Wang, Fuzhi1; Qian, Deping1; Tan, Zhan'ao1; Li, Liangjie1; Li, Shusheng1; Tu, Xiaohe1; Sun, Gang1; Hou, Xuliang1; Hou, Jianhui2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2013-07-24 |
| 卷号 | 5期号:14页码:6591-6597 |
| 关键词 | Planar Solar Cells Bulk Heterojunction Solar Cells Integrated Architecture D-a Copolymer Photo-cross-linkable Conjugated Polymers |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/am401263m |
| 英文摘要 | An integrated device architecture was constructed via vertical combination of planar and bulk heterojunctions by solution processing, where a cross-linked D-A copolymer (PEDTTT-Br25) was inserted between a PEDOT:PSS layer and the blended photoactive layer. PBDTTT-Br25 can readily undergo photo crosslinking to form an insoluble robust film via ultraviolet irradiation after solution-deposition, which enables the subsequent solution processing of a photoactive layer on the robust surface. The insertion of a pure PBDTTT-Br25 layer to build an integrated heterojunction could provide an additional donor/acceptor interface, which enables hole transport to the anode without interruption, thereby reducing the charge carrier recombination probability. The power conversion efficiency (PCE) of the polymer solar cell (PSC) with the integrated architecture reaches 5.24% under an AM1.5G illumination of 100 mW/cm(2), which is increased by 65%, in comparison with that of the reference single heterojunction device (3.17%), under the same experimental conditions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000322432500023 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46771]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tan, Zhan'ao |
| 作者单位 | 1.North China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewabl, New & Renewable Energy Beijing Key Lab, Beijing 102206, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Qi,Wang, Fuzhi,Qian, Deping,et al. Construction of Planar and Bulk Integrated Heterojunction Polymer Solar Cells Using Cross-Linkable D-A Copolymer[J]. ACS APPLIED MATERIALS & INTERFACES,2013,5(14):6591-6597. |
| APA | Xu, Qi.,Wang, Fuzhi.,Qian, Deping.,Tan, Zhan'ao.,Li, Liangjie.,...&Li, Yongfang.(2013).Construction of Planar and Bulk Integrated Heterojunction Polymer Solar Cells Using Cross-Linkable D-A Copolymer.ACS APPLIED MATERIALS & INTERFACES,5(14),6591-6597. |
| MLA | Xu, Qi,et al."Construction of Planar and Bulk Integrated Heterojunction Polymer Solar Cells Using Cross-Linkable D-A Copolymer".ACS APPLIED MATERIALS & INTERFACES 5.14(2013):6591-6597. |
入库方式： OAI收割
来源：化学研究所
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