中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Stretching Temperature Dependency of Lamellar Thickness in Stress-Induced Localized Melting and Recrystallized Polybutene-1

文献类型:期刊论文

作者Wang, Yaotao; Jiang, Zhiyong; Fu, Lianlian; Lu, Ying; Men, Yongfeng
刊名MACROMOLECULES
出版日期2013-10-08
卷号46期号:19页码:7874-7879
ISSN号0024-9297
DOI10.1021/ma401326g
英文摘要The structural parameters such as long spacing and thicknesses of crystalline lamellae and amorphous layers of polybutene-1 crystallized from quiescent melt at different isothermal temperatures and established by tensile stretching the isothermally crystallized samples at different temperatures via a stress induced localized melting and recrystallization process were determined by small-angle X-ray scattering experiments. In the two cases, almost parallel crystallization lines where reciprocal lamellar thickness and temperature at which the structure formed are in linear relationship were observed. As it turns out, the samples crystallized from the quiescent melt possess much thicker crystalline lamellae than those obtained via stretching at same temperature. The results yield two limiting temperatures for the formation of lamellae with infinite thickness in the two cases which can be understood by considering the influence of the stress on the thermodynamic parameters in the melt and thus the crystallization process.
语种英语
WOS记录号WOS:000326355200032
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/46773]  
专题中国科学院化学研究所
通讯作者Men, Yongfeng
作者单位Chinese Acad Sci, Changchun Inst Appl Chem, Univ Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Wang, Yaotao,Jiang, Zhiyong,Fu, Lianlian,et al. Stretching Temperature Dependency of Lamellar Thickness in Stress-Induced Localized Melting and Recrystallized Polybutene-1[J]. MACROMOLECULES,2013,46(19):7874-7879.
APA Wang, Yaotao,Jiang, Zhiyong,Fu, Lianlian,Lu, Ying,&Men, Yongfeng.(2013).Stretching Temperature Dependency of Lamellar Thickness in Stress-Induced Localized Melting and Recrystallized Polybutene-1.MACROMOLECULES,46(19),7874-7879.
MLA Wang, Yaotao,et al."Stretching Temperature Dependency of Lamellar Thickness in Stress-Induced Localized Melting and Recrystallized Polybutene-1".MACROMOLECULES 46.19(2013):7874-7879.

入库方式: OAI收割

来源:化学研究所

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