Synthesis, crystal structure and visible light emission of a new inorganic-organic hybrid pentaborate, [C6H14N][B5O6(OH)(4)]
文献类型：期刊论文
| 作者 | Luo, Wenjiao1,2; Wang, Yonggang1; Wen, Ting3; Zhang, Hao1; Lin, Xiaohuan1; Wang, Yingxia1; Liao, Fuhui1; Lin, Jianhua1 |
| 刊名 | JOURNAL OF MOLECULAR STRUCTURE
 |
| 出版日期 | 2013-09-24 |
| 卷号 | 1048页码:1-5 |
| 关键词 | Borate Crystal Structure Hydrothermal Luminescence White-light-emission |
| ISSN号 | 0022-2860 |
| DOI | 10.1016/j.molstruc.2013.05.023 |
| 英文摘要 | A new organic-inorganic hybrid pentaborate [C6H14N][B5O6(OH)(4)] (1) has been synthesised hydrothermally in aqueous solution and characterised by single-crystal X-ray diffraction, FT-IR, DTA-TG and photoluminescence spectroscopy. It crystallizes in the monoclinic system, space group P2(1)/c, with the lattice constants of a = 9.463 (2) angstrom, b = 14.005 (3) angstrom, c = 10.642 (2) angstrom, and beta = 93.82(3)degrees. The structure consists of isolated [B5O6(OH)(4)](-) groups interlinked by protonated cyclohexylamine via hydrogen bonding. Blue photoluminescence of 1 is observed upon UV excitation, which can be further enhanced and modified to near-white emission by thermal treatment. The maximum emissions and peak shapes of 1-250 degrees C are also tunable with various excitation wavelengths in the region of 350-470 nm. This compound provides a novel example of organically templated borate materials potential for display and lighting applications. (c) 2013 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000323468500001 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46821]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Yonggang |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 2.China Univ Geosci, Sch Mat Sci & Technol, Beijing 100190, Peoples R China 3.Huanghe Sci & Technol Coll, Inst Nanostruct Funct Mat, Zhengzhou 450006, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, Wenjiao,Wang, Yonggang,Wen, Ting,et al. Synthesis, crystal structure and visible light emission of a new inorganic-organic hybrid pentaborate, [C6H14N][B5O6(OH)(4)][J]. JOURNAL OF MOLECULAR STRUCTURE,2013,1048:1-5. |
| APA | Luo, Wenjiao.,Wang, Yonggang.,Wen, Ting.,Zhang, Hao.,Lin, Xiaohuan.,...&Lin, Jianhua.(2013).Synthesis, crystal structure and visible light emission of a new inorganic-organic hybrid pentaborate, [C6H14N][B5O6(OH)(4)].JOURNAL OF MOLECULAR STRUCTURE,1048,1-5. |
| MLA | Luo, Wenjiao,et al."Synthesis, crystal structure and visible light emission of a new inorganic-organic hybrid pentaborate, [C6H14N][B5O6(OH)(4)]".JOURNAL OF MOLECULAR STRUCTURE 1048(2013):1-5. |
入库方式： OAI收割
来源：化学研究所
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