Structural and electrochemical studies of Sm@D-3h-C-74 reveal a weak metal-cage interaction and a small band gap species
文献类型：期刊论文
| 作者 | Xu, Wei3; Hao, Yajuan1,2; Uhlik, Filip5; Shi, Zujin3; Slanina, Zdenek4; Feng, Lai1,2 |
| 刊名 | NANOSCALE
 |
| 出版日期 | 2013 |
| 卷号 | 5期号:21页码:10409-10413 |
| ISSN号 | 2040-3364 |
| DOI | 10.1039/c3nr03447j |
| 英文摘要 | A metallofullerene Sm@D-3h-C-74 that contains a divalent rare-earth metal has been studied structurally and electrochemically. The crystallographic analysis revealed that the endohedral Sm atom is more or less motional rather than being localized at a site where the pyracylene motif is nearby. This suggests a weaker metal-pyracylene interaction in Sm@D-3h-C-74 relative to that in MII@C-74 (M Group II metal), thus confirming the importance of the metal variety. The electrochemical studies showed a major difference between the redox properties of Sm@D-3h-C-74 and other Sm-fullerenes and indicated a small band gap for the title compound. |
| 语种 | 英语 |
| WOS记录号 | WOS:000325762000042 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46871]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shi, Zujin |
| 作者单位 | 1.Soochow Univ, Jiangsu Key Lab Thin Films, Suzhou 215006, Peoples R China 2.Soochow Univ, Sch Energy, Suzhou 215006, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China 4.Natl Inst Nat Sci, Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan 5.Charles Univ Prague, Fac Sci, Dept Phys & Macromol Chem, Prague 12843 2, Czech Republic |
| 推荐引用方式 GB/T 7714 | Xu, Wei,Hao, Yajuan,Uhlik, Filip,et al. Structural and electrochemical studies of Sm@D-3h-C-74 reveal a weak metal-cage interaction and a small band gap species[J]. NANOSCALE,2013,5(21):10409-10413. |
| APA | Xu, Wei,Hao, Yajuan,Uhlik, Filip,Shi, Zujin,Slanina, Zdenek,&Feng, Lai.(2013).Structural and electrochemical studies of Sm@D-3h-C-74 reveal a weak metal-cage interaction and a small band gap species.NANOSCALE,5(21),10409-10413. |
| MLA | Xu, Wei,et al."Structural and electrochemical studies of Sm@D-3h-C-74 reveal a weak metal-cage interaction and a small band gap species".NANOSCALE 5.21(2013):10409-10413. |
入库方式： OAI收割
来源：化学研究所
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