Controlling the surface composition of PCBM in P3HT/PCBM blend films by using mixed solvents with different evaporation rates
文献类型：期刊论文
| 作者 | Sun, Yue; Liu, Jian-gang; Ding, Yan; Han, Yan-chun |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2013-07-01 |
| 卷号 | 31期号:7页码:1029-1037 |
| 关键词 | P3ht Pcbm Surface Composition Mixed Solvents Slow Evaporation |
| ISSN号 | 0256-7679 |
| DOI | 10.1007/s10118-013-1295-7 |
| 英文摘要 | The surface composition of poly(3-hexylthiophene-2,5-diyl) and fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester (P3HT/PCBM) blend films could be changed by controlling the film formation process via using mixed solvents with different evaporation rates. The second solvent, with a higher boiling point than that of the first solvent and much better solubility for PCBM than P3HT, is chosen to mix with the first solvent with a lower boiling point and good solubility for both PCBM and P3HT. The slow evaporation rate of the second solvent provides enough time for PCBM to diffuse upwards during the solvent evaporation. Thus, the weight ratio of PCBM and P3HT (m (PCBM)/m (P3HT)) at surface of the blend films was varied from ca. 0.1 to ca. 0.72, i.e., it increases about seven times by changing from single solvent to mixed solvents. Meanwhile, the mixed solvents were in favor to form P3HT naonofiber network and enhance phase separation of P3HT/PCBM blend films. As a result, the power conversion efficiency of the device from mixed solvents with slow evaporation process was about 1.5 times of the one from single solvents. |
| 语种 | 英语 |
| WOS记录号 | WOS:000319477800009 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46939]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, Yan-chun |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Yue,Liu, Jian-gang,Ding, Yan,et al. Controlling the surface composition of PCBM in P3HT/PCBM blend films by using mixed solvents with different evaporation rates[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2013,31(7):1029-1037. |
| APA | Sun, Yue,Liu, Jian-gang,Ding, Yan,&Han, Yan-chun.(2013).Controlling the surface composition of PCBM in P3HT/PCBM blend films by using mixed solvents with different evaporation rates.CHINESE JOURNAL OF POLYMER SCIENCE,31(7),1029-1037. |
| MLA | Sun, Yue,et al."Controlling the surface composition of PCBM in P3HT/PCBM blend films by using mixed solvents with different evaporation rates".CHINESE JOURNAL OF POLYMER SCIENCE 31.7(2013):1029-1037. |
入库方式： OAI收割
来源：化学研究所
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