Fabricating graphene oxide/poly(3-butylthiophene) hybrid materials with different morphologies and crystal structures
文献类型：期刊论文
| 作者 | Zhou, Xun1,2,3; Chen, Zhaobin1; Qu, Yunpeng1; Su, Qing1,2; Yang, Xiaoniu1,2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2013 |
| 卷号 | 3期号:13页码:4254-4260 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c3ra00032j |
| 英文摘要 | In this study, graphene oxide (GO) based hybrid materials with poly(3-butylthiophene) (P3BT) having various morphologies and crystal structures are fabricated through different approaches. The first kind of GO/P3BT hybrid material was prepared by aging GO/P3BT mixture in o-dichlorobenzene (ODCB) solvent, in which the P3BT molecules grow on GO surface and crystallize into semi-spherulites composed of nanoribbons. In this GO/P3BT hybrid material, P3BT crystals are in From II structure with a pi-stacking distance of 0.47 nm and the P3BT nanoribbons with maximum width of 200 nm preferentially grow along the pi-stacking direction. After thermal treatment, the GO/Form II P3BT hybrid material could be easily transformed into GO/Form I P3BT hybrid material with unchanged nanoribbon morphology but a modified pi-stacking distance of 0.38 nm. If anisole is added to the fresh GO/P3BT solution in ODCB solvent, a third hybrid material, i.e., GO/P3BT nanowhiskers in Form I structure, was obtained. This work would be of benefit for the further understanding of P3BT crystallization behavior in the presence of GO and these hybrid materials would also provide potential platforms for further morphology-property study and crystal structure-property study on GO/conjugated polymer hybrid materials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000315818200023 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46967]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhou, Xun |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Composites Engn Lab, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Xun,Chen, Zhaobin,Qu, Yunpeng,et al. Fabricating graphene oxide/poly(3-butylthiophene) hybrid materials with different morphologies and crystal structures[J]. RSC ADVANCES,2013,3(13):4254-4260. |
| APA | Zhou, Xun,Chen, Zhaobin,Qu, Yunpeng,Su, Qing,&Yang, Xiaoniu.(2013).Fabricating graphene oxide/poly(3-butylthiophene) hybrid materials with different morphologies and crystal structures.RSC ADVANCES,3(13),4254-4260. |
| MLA | Zhou, Xun,et al."Fabricating graphene oxide/poly(3-butylthiophene) hybrid materials with different morphologies and crystal structures".RSC ADVANCES 3.13(2013):4254-4260. |
入库方式： OAI收割
来源：化学研究所
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