Preparation of Poly(serine ester)s by Ring-opening Polymerization of N-Trityl Serine Lactone Under Catalysis of ZnEt2
文献类型：期刊论文
| 作者 | Wei Ying1,2; Li Xiao-yuan1; Jing Xia-bin1; Chen Xue-si1; Huang Yu-bin1 |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| 出版日期 | 2013-02-01 |
| 卷号 | 29期号:1页码:177-182 |
| 关键词 | Diethyl Zinc Catalyst Poly(Serine Lactone) Pseudopoly(Amino Acid) Ring-opening Polymerization Diethyl Zinc(Znet2) |
| ISSN号 | 1005-9040 |
| DOI | 10.1007/s40242-013-2355-9 |
| 英文摘要 | Poly(N-trityl serine lactone)(PTSL) and mPEG-block-poly(N-trityl serine lactone)(mPEG-b-PTSL, PEG=polyethylene glycol) were synthesized via the ring-opening polymerization of N-trityl serine lactone(TSL) with diethyl zinc(ZnEt2) as catalyst. The structures of these polymers were confirmed with hydrogen nuclear magnetic resonance(H-1 NMR) spectroscopy, carbon nuclear magnetic resonance(C-13 NMR) spectroscopy and infrared(IR) spectrometer. The thermal decomposition temperature and glass transition temperature of PTSL were 241 and 161 C, respectively. A series of mPEG-b-PTSL with different molecular weights(M-n's from 7000 to 32000) was obtained by tuning the TSL/mPEG feed ratio. After the removal of the trityl groups, mPEG-block-poly(serine lactone)(mPEG-b-PSL) was obtained as a new kind of cationic block copolymer. Low cytotoxicity of these polymers to L929 cells was confirmed via 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide(MTT) assay. |
| 语种 | 英语 |
| WOS记录号 | WOS:000317165700034 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/46973]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang Yu-bin |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei Ying,Li Xiao-yuan,Jing Xia-bin,et al. Preparation of Poly(serine ester)s by Ring-opening Polymerization of N-Trityl Serine Lactone Under Catalysis of ZnEt2[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2013,29(1):177-182. |
| APA | Wei Ying,Li Xiao-yuan,Jing Xia-bin,Chen Xue-si,&Huang Yu-bin.(2013).Preparation of Poly(serine ester)s by Ring-opening Polymerization of N-Trityl Serine Lactone Under Catalysis of ZnEt2.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,29(1),177-182. |
| MLA | Wei Ying,et al."Preparation of Poly(serine ester)s by Ring-opening Polymerization of N-Trityl Serine Lactone Under Catalysis of ZnEt2".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 29.1(2013):177-182. |
入库方式： OAI收割
来源：化学研究所
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