On Off On Fluorescent Carbon Dot Nanosensor for Recognition of Chromium(VI) and Ascorbic Acid Based on the Inner Filter Effect
文献类型：期刊论文
| 作者 | Zheng, Min1; Xie, Zhigang2; Qu, Dan1,3; Li, Di1; Du, Peng1,3; Jing, Xiabin2; Sun, Zaicheng1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2013-12-25 |
| 卷号 | 5期号:24页码:13242-13247 |
| 关键词 | On-off-on Fluorescent Carbon Dots Nanochemosensor Inner Filter Effect (Ife) Chromium(Vi) Ascorbic Acid |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/am4042355 |
| 英文摘要 | Chromium(VI) [Cr(VI)] is considered as a severe environmental pollutant, due to its highly toxic and carcinogenic properties. Therefore, low cost, highly sensitive sensors for the determination of Cr(VI) are highly demanded. It is well-known that highly luminescent carbon dots (CDs) have been successfully applied as fluorescent nanosensors for pH, ions, and molecular substances. In the present work, we have demonstrated an on-off fluorescent CD probe for detecting Cr(VI) based on the inner filter effect (IFE) because the absorption bands of Cr(IV) fully covered the emission and excitation bands of CDs. This CD-based nanosensor provides obvious advantages of simplicity, convenience, rapid response, high selectivity, and sensitivity, which have potential application for the detection of Cr(VI) in the environmental industry. In addition, because Cr(VI) can be reduced to low valent chromium species easily by reductant, resulting in the elimination of the WE and recovery of CD fluorescence, the CD-Cr(VI) mixture could behave as an off-on type fluorescent probe for reductant. We employed ascorbic acid (AA) as an example molecule to demonstrate this off-on type fluorescent probe. |
| 语种 | 英语 |
| WOS记录号 | WOS:000329137400063 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47043]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xie, Zhigang |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, State Key Lab Luminescence & Applicat, Changchun 130033, Jilin, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Min,Xie, Zhigang,Qu, Dan,et al. On Off On Fluorescent Carbon Dot Nanosensor for Recognition of Chromium(VI) and Ascorbic Acid Based on the Inner Filter Effect[J]. ACS APPLIED MATERIALS & INTERFACES,2013,5(24):13242-13247. |
| APA | Zheng, Min.,Xie, Zhigang.,Qu, Dan.,Li, Di.,Du, Peng.,...&Sun, Zaicheng.(2013).On Off On Fluorescent Carbon Dot Nanosensor for Recognition of Chromium(VI) and Ascorbic Acid Based on the Inner Filter Effect.ACS APPLIED MATERIALS & INTERFACES,5(24),13242-13247. |
| MLA | Zheng, Min,et al."On Off On Fluorescent Carbon Dot Nanosensor for Recognition of Chromium(VI) and Ascorbic Acid Based on the Inner Filter Effect".ACS APPLIED MATERIALS & INTERFACES 5.24(2013):13242-13247. |
入库方式： OAI收割
来源：化学研究所
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