A single-molecule magnet featuring a parallelogram [Dy-4(OCH2-)(4)] core and two magnetic relaxation processes
文献类型：期刊论文
| 作者 | Liu, Cai-Ming; Zhang, De-Qing; Zhu, Dao-Ben |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2013 |
| 卷号 | 42期号:41页码:14813-14818 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c3dt51785c |
| 英文摘要 | An alkoxido-bridged tetranuclear Dy(III) complex, [Dy-4(H3L)(2)(OAc)(6)]center dot 2EtOH {1, H6L = 1,3-bis[tris(hydroxymethyl) methylamino] propane}, has been solvothermally synthesized and characterized. An X-ray crystallographic study revealed that complex 1 possesses a novel "parallelogram" [Dy-4(OCH2-)(4)] core, and a new binding mode eta(3):eta(3):eta(1):eta(1):eta(1):eta(2):mu(4) of the Bis-tris propane ligand was observed. Magnetic investigations indicated that it is a single-molecule magnet (SMM), showing two distinct magnetic relaxation processes with the energy barriers of 44 K and 107 K, respectively. Such a two-step magnetic relaxation process could be well described by the sum of two modified Debye functions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000325369200022 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47051]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Cai-Ming |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Ctr Mol Sci, Inst Chem,Key Lab Organ Solids, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Cai-Ming,Zhang, De-Qing,Zhu, Dao-Ben. A single-molecule magnet featuring a parallelogram [Dy-4(OCH2-)(4)] core and two magnetic relaxation processes[J]. DALTON TRANSACTIONS,2013,42(41):14813-14818. |
| APA | Liu, Cai-Ming,Zhang, De-Qing,&Zhu, Dao-Ben.(2013).A single-molecule magnet featuring a parallelogram [Dy-4(OCH2-)(4)] core and two magnetic relaxation processes.DALTON TRANSACTIONS,42(41),14813-14818. |
| MLA | Liu, Cai-Ming,et al."A single-molecule magnet featuring a parallelogram [Dy-4(OCH2-)(4)] core and two magnetic relaxation processes".DALTON TRANSACTIONS 42.41(2013):14813-14818. |
入库方式： OAI收割
来源：化学研究所
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