Constructional details of polystyrene-block-poly(4-vinylpyridine) ordered thin film morphology
文献类型：期刊论文
| 作者 | Xue, Feifei1; Li, Hongfei2; An, Lijia2; Jiang, Shichun1 |
| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2013-06-01 |
| 卷号 | 399页码:62-67 |
| 关键词 | Diblock Copolymer Thin Film Ps-b-p4vp Phase Image Surface Microdomain Distinguishing |
| ISSN号 | 0021-9797 |
| DOI | 10.1016/j.jcis.2013.02.033 |
| 英文摘要 | One of the most important issues for spin-coated diblock copolymer thin films is to distinguish the blocks by common techniques, especially for the diblock copolymers containing one block could form active domain. Aiming different estimations on the composition of surface microdomains in polystyrene-block-poly (4-vinylpyridine) (PS-b-P4VP) atomic force microscope (AFM) phase images, AFM, transmission electron microscopy, and droplet shape analyzer were used to identify the constructional details of the polymer thin film morphology. It was confirmed that PS block is harder than P4VP block in symmetric PS-b-P4VP films and corresponds to brighter regions in AFM phase image. It is helpful to distinguish the nanodomains that originate from the different blocks in PS-b-P4VP thin films. The structure evolutions of PS-b-P4VP film annealed with different selective solvents were studied and discussed. The results indicated that the core-corona inversion process is due to the cores of micelles swell and coalesce together rather than local reorganization of the chains. (C) 2013 Elsevier.Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000317809200009 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47061]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Hongfei |
| 作者单位 | 1.Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, Feifei,Li, Hongfei,An, Lijia,et al. Constructional details of polystyrene-block-poly(4-vinylpyridine) ordered thin film morphology[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2013,399:62-67. |
| APA | Xue, Feifei,Li, Hongfei,An, Lijia,&Jiang, Shichun.(2013).Constructional details of polystyrene-block-poly(4-vinylpyridine) ordered thin film morphology.JOURNAL OF COLLOID AND INTERFACE SCIENCE,399,62-67. |
| MLA | Xue, Feifei,et al."Constructional details of polystyrene-block-poly(4-vinylpyridine) ordered thin film morphology".JOURNAL OF COLLOID AND INTERFACE SCIENCE 399(2013):62-67. |
入库方式： OAI收割
来源：化学研究所
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