Synthesis of functionalized cyclotriveratrylene analogues with C-1-symmetry and the application for 1,4-Michael addition of alcohols to unsaturated aryl ketone
文献类型：期刊论文
| 作者 | Song, Jing-Ru; Huang, Zhi-Tang; Zheng, Qi-Yu |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2013-09-02 |
| 卷号 | 69期号:35页码:7308-7313 |
| 关键词 | Cyclotriveratrylene C-1-symmetry Chemical Resolution N-heterocyclic Carbene Michael Addition |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2013.06.077 |
| 英文摘要 | C-1-symmetric cyclotriveratrylene analogues 2-8 with various functional groups at one benzene moiety were prepared starting from the selectively demethylated compound 1. Through the chemical resolution, a pair of enantiomers of C-1-symmeric compound 1 could be separated with gram scale. Compound 8, which possessed an N-linked imidazolium unit at the upper rim of the macrocyclic skeleton through a methylene linker, was successfully applied to 1,4-Michael addition reaction of alcohol to unsaturated aryl ketone. Its supramolecular catalytic activity as an NHC precursor was demonstrated by the chem-selectivity to aromatic alcohol than alkyl alcohol. (C) 2013 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000322557500015 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47089]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zheng, Qi-Yu |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Jing-Ru,Huang, Zhi-Tang,Zheng, Qi-Yu. Synthesis of functionalized cyclotriveratrylene analogues with C-1-symmetry and the application for 1,4-Michael addition of alcohols to unsaturated aryl ketone[J]. TETRAHEDRON,2013,69(35):7308-7313. |
| APA | Song, Jing-Ru,Huang, Zhi-Tang,&Zheng, Qi-Yu.(2013).Synthesis of functionalized cyclotriveratrylene analogues with C-1-symmetry and the application for 1,4-Michael addition of alcohols to unsaturated aryl ketone.TETRAHEDRON,69(35),7308-7313. |
| MLA | Song, Jing-Ru,et al."Synthesis of functionalized cyclotriveratrylene analogues with C-1-symmetry and the application for 1,4-Michael addition of alcohols to unsaturated aryl ketone".TETRAHEDRON 69.35(2013):7308-7313. |
入库方式： OAI收割
来源：化学研究所
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