中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Platinum-Based Poly(Aryleneethynylene) Polymers Containing Thiazolothiazole Group with High Hole Mobilities for Field-Effect Transistor Applications

文献类型:期刊论文

作者Yan, Lei1,2,3; Zhao, Yan4; Wang, Xiaohui1,2; Wang, Xing-Zhu1,2; Wong, Wai-Yeung5,6; Liu, Yunqi4; Wu, Weiping4; Xiao, Qingzhen1,2; Wang, Guo1,2; Zhou, Xuan1,2
刊名MACROMOLECULAR RAPID COMMUNICATIONS
出版日期2012-04-13
卷号33期号:6-7页码:603-609
关键词Acetylide Metallopolymer Organic Field-effect Transistors Platinum Thiazolothiazole
ISSN号1022-1336
DOI10.1002/marc.201200018
英文摘要Two solution-processable platinum-acetylide polymers functionalized with the electron-deficient thiazolothiazole spacer are synthesized and show absorption features spanning from 320 to 600 nm and optical bandgaps of 2.15 and 2.05 eV. The spin-coated polymer thin films of both materials exhibit p-channel field-effect charge transport characteristics with impressive peak field-effect charge-carrier mobilities of (2.12.8) x 10-2 cm2 V-1 s-1 and on/off ratios of (0.81.0) x 105 for the holes. The high hole mobility value reported for one of the polymers is among the highest reported for metallopolyynes to date. It is also shown that the hole mobility can be notably increased by extending the conjugation length of the chain from the monothienyl to the bithienyl segment on each side of the thiazolothiazole ring.
语种英语
WOS记录号WOS:000302537600024
出版者WILEY-V C H VERLAG GMBH
源URL[http://ir.iccas.ac.cn/handle/121111/47127]  
专题中国科学院化学研究所
通讯作者Wang, Xing-Zhu
作者单位1.Xiangtan Univ, Coll Chem, Xiangtan 411105, Hunan, Peoples R China
2.Xiangtan Univ, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Hunan, Peoples R China
3.Xiangtan Univ, Key Lab Low Dimens Mat & Applicat Technol, Minist Educ, Xiangtan 411105, Hunan, Peoples R China
4.Chinese Acad Sci, Key Lab Organ Solid, Inst Chem, Beijing 100190, Peoples R China
5.Hong Kong Baptist Univ, Inst Mol Funct Mat, Kowloon Tong, Hong Kong, Peoples R China
6.Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China
7.S China Univ Technol, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
8.S China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Yan, Lei,Zhao, Yan,Wang, Xiaohui,et al. Platinum-Based Poly(Aryleneethynylene) Polymers Containing Thiazolothiazole Group with High Hole Mobilities for Field-Effect Transistor Applications[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2012,33(6-7):603-609.
APA Yan, Lei.,Zhao, Yan.,Wang, Xiaohui.,Wang, Xing-Zhu.,Wong, Wai-Yeung.,...&Wu, Hongbin.(2012).Platinum-Based Poly(Aryleneethynylene) Polymers Containing Thiazolothiazole Group with High Hole Mobilities for Field-Effect Transistor Applications.MACROMOLECULAR RAPID COMMUNICATIONS,33(6-7),603-609.
MLA Yan, Lei,et al."Platinum-Based Poly(Aryleneethynylene) Polymers Containing Thiazolothiazole Group with High Hole Mobilities for Field-Effect Transistor Applications".MACROMOLECULAR RAPID COMMUNICATIONS 33.6-7(2012):603-609.

入库方式: OAI收割

来源:化学研究所

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