Platinum-Based Poly(Aryleneethynylene) Polymers Containing Thiazolothiazole Group with High Hole Mobilities for Field-Effect Transistor Applications
文献类型:期刊论文
作者 | Yan, Lei1,2,3; Zhao, Yan4; Wang, Xiaohui1,2; Wang, Xing-Zhu1,2; Wong, Wai-Yeung5,6; Liu, Yunqi4; Wu, Weiping4; Xiao, Qingzhen1,2; Wang, Guo1,2; Zhou, Xuan1,2 |
刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
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出版日期 | 2012-04-13 |
卷号 | 33期号:6-7页码:603-609 |
关键词 | Acetylide Metallopolymer Organic Field-effect Transistors Platinum Thiazolothiazole |
ISSN号 | 1022-1336 |
DOI | 10.1002/marc.201200018 |
英文摘要 | Two solution-processable platinum-acetylide polymers functionalized with the electron-deficient thiazolothiazole spacer are synthesized and show absorption features spanning from 320 to 600 nm and optical bandgaps of 2.15 and 2.05 eV. The spin-coated polymer thin films of both materials exhibit p-channel field-effect charge transport characteristics with impressive peak field-effect charge-carrier mobilities of (2.12.8) x 10-2 cm2 V-1 s-1 and on/off ratios of (0.81.0) x 105 for the holes. The high hole mobility value reported for one of the polymers is among the highest reported for metallopolyynes to date. It is also shown that the hole mobility can be notably increased by extending the conjugation length of the chain from the monothienyl to the bithienyl segment on each side of the thiazolothiazole ring. |
语种 | 英语 |
WOS记录号 | WOS:000302537600024 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/47127] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang, Xing-Zhu |
作者单位 | 1.Xiangtan Univ, Coll Chem, Xiangtan 411105, Hunan, Peoples R China 2.Xiangtan Univ, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Hunan, Peoples R China 3.Xiangtan Univ, Key Lab Low Dimens Mat & Applicat Technol, Minist Educ, Xiangtan 411105, Hunan, Peoples R China 4.Chinese Acad Sci, Key Lab Organ Solid, Inst Chem, Beijing 100190, Peoples R China 5.Hong Kong Baptist Univ, Inst Mol Funct Mat, Kowloon Tong, Hong Kong, Peoples R China 6.Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China 7.S China Univ Technol, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China 8.S China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Yan, Lei,Zhao, Yan,Wang, Xiaohui,et al. Platinum-Based Poly(Aryleneethynylene) Polymers Containing Thiazolothiazole Group with High Hole Mobilities for Field-Effect Transistor Applications[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2012,33(6-7):603-609. |
APA | Yan, Lei.,Zhao, Yan.,Wang, Xiaohui.,Wang, Xing-Zhu.,Wong, Wai-Yeung.,...&Wu, Hongbin.(2012).Platinum-Based Poly(Aryleneethynylene) Polymers Containing Thiazolothiazole Group with High Hole Mobilities for Field-Effect Transistor Applications.MACROMOLECULAR RAPID COMMUNICATIONS,33(6-7),603-609. |
MLA | Yan, Lei,et al."Platinum-Based Poly(Aryleneethynylene) Polymers Containing Thiazolothiazole Group with High Hole Mobilities for Field-Effect Transistor Applications".MACROMOLECULAR RAPID COMMUNICATIONS 33.6-7(2012):603-609. |
入库方式: OAI收割
来源:化学研究所
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