Metal-Ion-Promoted Electron Transfer between Tetrathiafulvalene and Quinone Units Within a Calix[4]arene Framework and Tuning through Coordination of the Neighboring Crown Ether with a Sodium Cation
文献类型:期刊论文
作者 | Sun, Fei1,2; Hu, Fang1,2; Zhang, Guanxin1; Zhang, Deqing1 |
刊名 | CHEMISTRY-AN ASIAN JOURNAL
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出版日期 | 2012-01-02 |
卷号 | 7期号:1页码:183-189 |
关键词 | Calixarenes Electron Transfer Metal-ion Coordination Quinones Tetrathiafulvalene |
ISSN号 | 1861-4728 |
DOI | 10.1002/asia.201100560 |
英文摘要 | A new calix[4]arene 1 with tetrathiafulvalene (TTF), quinone, and crown ether units in the lower rim was designed and synthesized with the aim to investigate the possibility to tune the metal-ion promoted electron transfer by coordination of the crown ether unit with additional metal ions. Both absorption and electron spin resonance (ESR) spectroscopic studies clearly indicate that electron transfer occurs efficiently from TTF to the quinone units in the presence of Sc3+/Pb2+/Zn2+. Moreover, the intramolecular electron transfer within 1 induced by Zn2+ can be switched off by addition of Na+ and further turned on by addition of either Sc3+ or Pb2+. |
语种 | 英语 |
WOS记录号 | WOS:000298483600024 |
出版者 | WILEY-BLACKWELL |
源URL | [http://ir.iccas.ac.cn/handle/121111/47159] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhang, Guanxin |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Organ Solids Lab, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, Fei,Hu, Fang,Zhang, Guanxin,et al. Metal-Ion-Promoted Electron Transfer between Tetrathiafulvalene and Quinone Units Within a Calix[4]arene Framework and Tuning through Coordination of the Neighboring Crown Ether with a Sodium Cation[J]. CHEMISTRY-AN ASIAN JOURNAL,2012,7(1):183-189. |
APA | Sun, Fei,Hu, Fang,Zhang, Guanxin,&Zhang, Deqing.(2012).Metal-Ion-Promoted Electron Transfer between Tetrathiafulvalene and Quinone Units Within a Calix[4]arene Framework and Tuning through Coordination of the Neighboring Crown Ether with a Sodium Cation.CHEMISTRY-AN ASIAN JOURNAL,7(1),183-189. |
MLA | Sun, Fei,et al."Metal-Ion-Promoted Electron Transfer between Tetrathiafulvalene and Quinone Units Within a Calix[4]arene Framework and Tuning through Coordination of the Neighboring Crown Ether with a Sodium Cation".CHEMISTRY-AN ASIAN JOURNAL 7.1(2012):183-189. |
入库方式: OAI收割
来源:化学研究所
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