Soft coordination supramolecular polymers: novel materials for dual electrocatalysis
文献类型：期刊论文
| 作者 | Liang, Yawei1; Zhao, Jing1,2; Zhang, Dewen1; Yan, Yun1; Zhou, Yinglin1; Zhang, Xinxiang1; Huang, Jianbin1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2012 |
| 卷号 | 2期号:33页码:12732-12738 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c2ra22237j |
| 英文摘要 | We report in this paper a dual catalytic effect of water soluble soft coordination supramolecular polymers (SCSPs) based on Fe3+ and a bis-ligand. Upon assembling the Fe(III)-SCSPs onto electrodes via layer-by-layer technique, the electroactive films may lower the half-wave potential for all the tested molecules and enhance the current for neutral or oppositely charged electroactive species. The decrease of the half-wave potential was attributed to the mediation of the Fe(III)-SCSPs in electron transferring, whereas the enhancement of current is a consequence of accumulation of electrons in the films. We verified that this dual catalytic effect is general to neutral and cationic redox active molecules, and can be used to detect hydrogen peroxide owing to the significant enlargement of catalytic current. Our results proved that the water soluble soft coordination supramolecular polymers containing metal centers are indeed a novel class of advanced catalytic materials, which may open a new vista on the design and study of materials of this class. |
| 语种 | 英语 |
| WOS记录号 | WOS:000312149600032 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47207]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liang, Yawei |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Key Lab Biochem & Mol Engn, Beijing Natl Lab Mol Sci BNLMS, Beijing 100871, Peoples R China 2.Univ Calif Davis, Dept Chem, Davis, CA 95616 USA |
| 推荐引用方式 GB/T 7714 | Liang, Yawei,Zhao, Jing,Zhang, Dewen,et al. Soft coordination supramolecular polymers: novel materials for dual electrocatalysis[J]. RSC ADVANCES,2012,2(33):12732-12738. |
| APA | Liang, Yawei.,Zhao, Jing.,Zhang, Dewen.,Yan, Yun.,Zhou, Yinglin.,...&Huang, Jianbin.(2012).Soft coordination supramolecular polymers: novel materials for dual electrocatalysis.RSC ADVANCES,2(33),12732-12738. |
| MLA | Liang, Yawei,et al."Soft coordination supramolecular polymers: novel materials for dual electrocatalysis".RSC ADVANCES 2.33(2012):12732-12738. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。