Synthesis, characterization and ethylene oligomerization behavior of N-(2-alkyl-5,6,7-trihydroquinolin-8-ylidene)arylaminonickel(II) dichlorides
文献类型：期刊论文
| 作者 | Chai, Wenbin1,2; Yu, Jiangang2; Wang, Lin2; Hu, Xinquan1; Redshaw, Carl3; Sun, Wen-Hua2
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| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2012-04-30 |
| 卷号 | 385页码:21-26 |
| 关键词 | Nickel(Ii) Complex Ethylene Oligomerization N-(2-alkyl-5 6 7-trihydroquinolin-8-ylidene)Arylamine |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2011.12.008 |
| 英文摘要 | A series of N-(2-alkyl-5,6,7-trihydroquinolin-8-ylidene)arylaminonickel(II) dichloride complexes were synthesized in a one-pot reaction with nickel dichloride. All nickel complexes were characterized by elemental and spectroscopic analysis. The molecular structures of representative nickel complexes, as determined by the single crystal X-ray diffraction, are reported. All nickel complexes, when treated with ethylaluminium sesquichloride (Et3Al2Cl3), showed high activities (up to 1.1 x 10(6) g mol(-1) h(-1)) for ethylene oligomerization, with good thermal stability at 80 degrees C at 10 atm ethylene. The influence of the reaction parameters on the catalytic behavior was investigated for these nickel-based systems, including variation of Al/Ni molar ratio and reaction temperature. (C) 2011 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000301455100003 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47255]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Hu, Xinquan |
| 作者单位 | 1.Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China 2.Chinese Acad Sci, Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England |
| 推荐引用方式 GB/T 7714 | Chai, Wenbin,Yu, Jiangang,Wang, Lin,et al. Synthesis, characterization and ethylene oligomerization behavior of N-(2-alkyl-5,6,7-trihydroquinolin-8-ylidene)arylaminonickel(II) dichlorides[J]. INORGANICA CHIMICA ACTA,2012,385:21-26. |
| APA | Chai, Wenbin,Yu, Jiangang,Wang, Lin,Hu, Xinquan,Redshaw, Carl,&Sun, Wen-Hua.(2012).Synthesis, characterization and ethylene oligomerization behavior of N-(2-alkyl-5,6,7-trihydroquinolin-8-ylidene)arylaminonickel(II) dichlorides.INORGANICA CHIMICA ACTA,385,21-26. |
| MLA | Chai, Wenbin,et al."Synthesis, characterization and ethylene oligomerization behavior of N-(2-alkyl-5,6,7-trihydroquinolin-8-ylidene)arylaminonickel(II) dichlorides".INORGANICA CHIMICA ACTA 385(2012):21-26. |
入库方式： OAI收割
来源：化学研究所
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