Tandem reaction of Morita-Baylis-Hillman alcohols derived from acrylic nitrile with 2-aminobenzimidazole in ionic liquid [BMIM]Cl/H2O
文献类型：期刊论文
| 作者 | Wang, Yan1,2; Liu, Li1,2; Wang, Dong1,2; Chen, Yong-Jun1,2 |
| 刊名 | CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
 |
| 出版日期 | 2012 |
| 卷号 | 90期号:1页码:85-91 |
| 关键词 | Morita Baylis Hillman Ionic Liquids Catalyst-free Aza-michael Addition |
| ISSN号 | 0008-4042 |
| DOI | 10.1139/V11-095 |
| 英文摘要 | The tandem reaction of Morita Baylis Hillman (MBH) alcohols 1a-1l derived from acrylic nitrile with 2-aminobenzimidazole (2) in ionic iquid (IL) [BMIM]Cl/H2O without additional catalyst was developed for the efficient synthesis of benzimidazol[1,2-a]pyrimidin-7(8H)-imine compounds. The tandem reaction included aza-Michael addition and intramolecular addition of an amino group to the cyano group in one pot. The combination of ionic liquid and water was found to be the best reaction medium, which played a role for accelerating the tandem reaction. |
| 语种 | 英语 |
| WOS记录号 | WOS:000299578600011 |
| 出版者 | CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47291]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Li |
| 作者单位 | 1.Chinese Acad Sci, BNLMS, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Yan Wang Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yan,Liu, Li,Wang, Dong,et al. Tandem reaction of Morita-Baylis-Hillman alcohols derived from acrylic nitrile with 2-aminobenzimidazole in ionic liquid [BMIM]Cl/H2O[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE,2012,90(1):85-91. |
| APA | Wang, Yan,Liu, Li,Wang, Dong,&Chen, Yong-Jun.(2012).Tandem reaction of Morita-Baylis-Hillman alcohols derived from acrylic nitrile with 2-aminobenzimidazole in ionic liquid [BMIM]Cl/H2O.CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE,90(1),85-91. |
| MLA | Wang, Yan,et al."Tandem reaction of Morita-Baylis-Hillman alcohols derived from acrylic nitrile with 2-aminobenzimidazole in ionic liquid [BMIM]Cl/H2O".CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE 90.1(2012):85-91. |
入库方式： OAI收割
来源：化学研究所
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