Probing the Conformational Transition of 2,2 '-Bipyridyl under External Field by Surface-Enhanced Raman Spectroscopy
文献类型：期刊论文
| 作者 | Luo, Zhixun1; Loo, Boon H.2; Cao, Xinqiang1; Peng, Aidong1; Yao, Jiannian1 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2012-02-02 |
| 卷号 | 116期号:4页码:2884-2890 |
| ISSN号 | 1932-7447 |
| DOI | 10.1021/jp208566d |
| 英文摘要 | Investigations on conformational transition of a small organic molecule are important to understand the conformation principles in chemistry and biology. We employed a low-temperature surface-enhanced Raman spectroscopy (LT-SERS) technique to probe the conformational changes of 2,2'-bipyridyl (22BPY) on Ag nanopartides at the presence of external fields. An electrochemical system was used to provide an electrostatic field, and a special magnet was designed to supply a magneto-static field. High-quality and distinguishable SERS spectra of 22BPY were obtained at the different environments, which show fingerprint labels for correlative conformations of the 22BPY. The conformational transition of 22BPY is implemented via its adsorption on the Ag nanoparticles by triggers of the external electric field and magnetic field. |
| 语种 | 英语 |
| WOS记录号 | WOS:000300462400028 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47343]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yao, Jiannian |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Towson Univ, Dept Chem, Towson, MD 21252 USA |
| 推荐引用方式 GB/T 7714 | Luo, Zhixun,Loo, Boon H.,Cao, Xinqiang,et al. Probing the Conformational Transition of 2,2 '-Bipyridyl under External Field by Surface-Enhanced Raman Spectroscopy[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2012,116(4):2884-2890. |
| APA | Luo, Zhixun,Loo, Boon H.,Cao, Xinqiang,Peng, Aidong,&Yao, Jiannian.(2012).Probing the Conformational Transition of 2,2 '-Bipyridyl under External Field by Surface-Enhanced Raman Spectroscopy.JOURNAL OF PHYSICAL CHEMISTRY C,116(4),2884-2890. |
| MLA | Luo, Zhixun,et al."Probing the Conformational Transition of 2,2 '-Bipyridyl under External Field by Surface-Enhanced Raman Spectroscopy".JOURNAL OF PHYSICAL CHEMISTRY C 116.4(2012):2884-2890. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。