中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
High efficiency polymer solar cells based on poly(3-hexylthiophene)/indene-C-70 bisadduct with solvent additive

文献类型:期刊论文

作者Guo, Xia1,2,3; Cui, Chaohua1; Zhang, Maojie1,2; Huo, Lijun2; Huang, Ye2; Hou, Jianhui2; Li, Yongfang1
刊名ENERGY & ENVIRONMENTAL SCIENCE
出版日期2012-07-01
卷号5期号:7页码:7943-7949
ISSN号1754-5692
DOI10.1039/c2ee21481d
英文摘要The photovoltaic performance of the polymer solar cells (PSCs) based on poly(3-hexylthiophene) (P3HT) as donor and indene-C-70 bisadduct (IC(70)BA) as acceptor was optimized by using 3 vol% high boiling point solvent additive of 1-chloronaphthalene (CN), N-methyl pyrrolidone (NMP), 1,8-octanedithiol (OT) or 1,8-diiodooctane (DIO) without solvent annealing. The optimized PSC based on P3HT : IC(70)BA (1 : 1, w/w) with 3 vol% CN and pre-thermal annealing at 150 degrees C for 10 min, exhibits a high power conversion efficiency (PCE) of 7.40% with V-oc of 0.87 V, J(sc) of 11.35 mA cm(-2) and FF of 75.0%, under the illumination of AM1.5G, 100mWcm(-2). The PCE of 7.40%, the Voc of 0.87 V, and the FF of 75.0% are all the highest values reported in the literature so far for P3HT-based PSCs. The high efficiency is due to the optimized P3HT/IC(70)BA interpenetrating network and stronger absorption of the active layer by using the additive treatment. Taking into account the advantages of thickness-insensitivity and good reproducibility of the photovoltaic performance of the P3HT-based PSCs as well as the simple device fabrication processes without the need of solvent annealing, the high-efficiency PSCs based on P3HT : IC(70)BA using CN additive are very promising for future commercialization of PSC devices.
语种英语
WOS记录号WOS:000305530900034
出版者ROYAL SOC CHEMISTRY
源URL[http://ir.iccas.ac.cn/handle/121111/47365]  
专题中国科学院化学研究所
通讯作者Guo, Xia
作者单位1.Chinese Acad Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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GB/T 7714
Guo, Xia,Cui, Chaohua,Zhang, Maojie,et al. High efficiency polymer solar cells based on poly(3-hexylthiophene)/indene-C-70 bisadduct with solvent additive[J]. ENERGY & ENVIRONMENTAL SCIENCE,2012,5(7):7943-7949.
APA Guo, Xia.,Cui, Chaohua.,Zhang, Maojie.,Huo, Lijun.,Huang, Ye.,...&Li, Yongfang.(2012).High efficiency polymer solar cells based on poly(3-hexylthiophene)/indene-C-70 bisadduct with solvent additive.ENERGY & ENVIRONMENTAL SCIENCE,5(7),7943-7949.
MLA Guo, Xia,et al."High efficiency polymer solar cells based on poly(3-hexylthiophene)/indene-C-70 bisadduct with solvent additive".ENERGY & ENVIRONMENTAL SCIENCE 5.7(2012):7943-7949.

入库方式: OAI收割

来源:化学研究所

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