Syntheses, structures and magnetic properties of five iron(II) coordination polymers with flexible bis(imidazole) and bis(triazole) ligands
文献类型：期刊论文
| 作者 | Zhu, Xia1; Wang, Xin-Yi2; Li, Bao-Long1; Wang, Ju1; Gao, Song3 |
| 刊名 | POLYHEDRON
 |
| 出版日期 | 2012-01-04 |
| 卷号 | 31期号:1页码:77-81 |
| 关键词 | Iron(Ii) Complexes Coordination Polymers Magnetic Properties Bis(Imidazole) Bis(Triazole) |
| ISSN号 | 0277-5387 |
| DOI | 10.1016/j.poly.2011.08.041 |
| 英文摘要 | Five iron(II) coordination polymers, {[Fe(bte)(2)(NCS)(2)][Fe(bte)(H2O)(2)(NCS)(2)]}(n) (1), [Fe(bime)(NCS)(2)](n) (2). [Fe(bime)(dca)(2)](n) (3). [Fe(bime)(2)(N-3)(2)](n) (4) and [Fe(btb)(2)(NCS)(2)](n) (5), were synthesized using the flexible ligands 1,2-bis(1,2,4-triazol-1-yl)ethane (bte), 1,2-bis(imidazol-1-yl)ethane (bime) and 1,4-bis(1,2,4-triazol-1-yl)butane (btb), together with NCS-, dicyanamide (dca) and N-3(-). The compound 1 contains two kinds of motifs (double chain and single chain) and forms a three-dimensional hydrogen bonded network; 2 and 3 contain one-dimensional triple chains; and 4 and 5 form two-dimensional (4,4) networks. The coordination anions (NCS-, dca and N-3(-)) and the structural characteristics of the ligands (bte, bime and btb) play an important role in the assembly of the topologies. Magnetic studies reveal that 1-5 remain in the high-spin state over the whole temperature range 2-300 K and no detectable spin-crossover is observed. (C) 2011 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000300642900011 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47395]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Bao-Long |
| 作者单位 | 1.Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China 2.Nanjing Univ, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China 3.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Xia,Wang, Xin-Yi,Li, Bao-Long,et al. Syntheses, structures and magnetic properties of five iron(II) coordination polymers with flexible bis(imidazole) and bis(triazole) ligands[J]. POLYHEDRON,2012,31(1):77-81. |
| APA | Zhu, Xia,Wang, Xin-Yi,Li, Bao-Long,Wang, Ju,&Gao, Song.(2012).Syntheses, structures and magnetic properties of five iron(II) coordination polymers with flexible bis(imidazole) and bis(triazole) ligands.POLYHEDRON,31(1),77-81. |
| MLA | Zhu, Xia,et al."Syntheses, structures and magnetic properties of five iron(II) coordination polymers with flexible bis(imidazole) and bis(triazole) ligands".POLYHEDRON 31.1(2012):77-81. |
入库方式： OAI收割
来源：化学研究所
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