Improved dispersibility of graphene oxide in o-dichlorobenzene by adding a poly(3-alkylthiophene)
文献类型:期刊论文
作者 | Zhou, Xun1,2,3; Yang, Xiaoniu1,2 |
刊名 | CARBON
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出版日期 | 2012-10-01 |
卷号 | 50期号:12页码:4566-4572 |
ISSN号 | 0008-6223 |
DOI | 10.1016/j.carbon.2012.05.041 |
英文摘要 | The dispersibility of graphene oxide (GO) in o-dichlorobenzene was improved by adding poly(3-hexylthiophene) (P3HT). The resulting GO dispersion was stable for up to one week. Transmission electron microscopy, UV-Vis spectroscopy, Raman spectroscopy and photoluminescence spectroscopy indicated that the crystallization of P3HT molecules on the GO surface prevented GO sheets from strong pi-pi interactions, and thus greatly increased the dispersibility of GO in organic solvent. The crystallization of P3HT molecules is a physical and reversible process, and it is time and temperature dependent. The crystallization process becomes remarkable with prolonged aging time and decreasing temperature. Other conjugated polymers, including poly(3-butylthiophene) and poly(3-hexylthiophene)-b-poly(epsilon-caprolactone), were further examined by the same method, and similar phenomena were also observed, indicating that the simple method of using a poly(3-alkylthiophene) to improve GO dispersibility in organic solvent is universal. (C) 2012 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000307206600029 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/47397] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Yang, Xiaoniu |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Composites Engn Lab, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, Xun,Yang, Xiaoniu. Improved dispersibility of graphene oxide in o-dichlorobenzene by adding a poly(3-alkylthiophene)[J]. CARBON,2012,50(12):4566-4572. |
APA | Zhou, Xun,&Yang, Xiaoniu.(2012).Improved dispersibility of graphene oxide in o-dichlorobenzene by adding a poly(3-alkylthiophene).CARBON,50(12),4566-4572. |
MLA | Zhou, Xun,et al."Improved dispersibility of graphene oxide in o-dichlorobenzene by adding a poly(3-alkylthiophene)".CARBON 50.12(2012):4566-4572. |
入库方式: OAI收割
来源:化学研究所
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