中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Improved dispersibility of graphene oxide in o-dichlorobenzene by adding a poly(3-alkylthiophene)

文献类型:期刊论文

作者Zhou, Xun1,2,3; Yang, Xiaoniu1,2
刊名CARBON
出版日期2012-10-01
卷号50期号:12页码:4566-4572
ISSN号0008-6223
DOI10.1016/j.carbon.2012.05.041
英文摘要The dispersibility of graphene oxide (GO) in o-dichlorobenzene was improved by adding poly(3-hexylthiophene) (P3HT). The resulting GO dispersion was stable for up to one week. Transmission electron microscopy, UV-Vis spectroscopy, Raman spectroscopy and photoluminescence spectroscopy indicated that the crystallization of P3HT molecules on the GO surface prevented GO sheets from strong pi-pi interactions, and thus greatly increased the dispersibility of GO in organic solvent. The crystallization of P3HT molecules is a physical and reversible process, and it is time and temperature dependent. The crystallization process becomes remarkable with prolonged aging time and decreasing temperature. Other conjugated polymers, including poly(3-butylthiophene) and poly(3-hexylthiophene)-b-poly(epsilon-caprolactone), were further examined by the same method, and similar phenomena were also observed, indicating that the simple method of using a poly(3-alkylthiophene) to improve GO dispersibility in organic solvent is universal. (C) 2012 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000307206600029
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/47397]  
专题中国科学院化学研究所
通讯作者Yang, Xiaoniu
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Composites Engn Lab, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhou, Xun,Yang, Xiaoniu. Improved dispersibility of graphene oxide in o-dichlorobenzene by adding a poly(3-alkylthiophene)[J]. CARBON,2012,50(12):4566-4572.
APA Zhou, Xun,&Yang, Xiaoniu.(2012).Improved dispersibility of graphene oxide in o-dichlorobenzene by adding a poly(3-alkylthiophene).CARBON,50(12),4566-4572.
MLA Zhou, Xun,et al."Improved dispersibility of graphene oxide in o-dichlorobenzene by adding a poly(3-alkylthiophene)".CARBON 50.12(2012):4566-4572.

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来源:化学研究所

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