Syntheses, structures and properties of chiral dinuclear zinc complexes with Schiff-base ligands
文献类型:期刊论文
作者 | Wen, He-Rui1; Wang, Ying1; Chen, Jing-Lin1; Tang, Yun-Zhi1; Liao, Jin-Sheng1; Liu, Cai-Ming2 |
刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
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出版日期 | 2012-06-01 |
卷号 | 20页码:303-306 |
关键词 | Zinc Complexes Chiral Schiff-base Crystal Structure Circular Dichroism Spectrum Luminescence Properties |
ISSN号 | 1387-7003 |
DOI | 10.1016/j.inoche.2012.03.036 |
英文摘要 | Two couples of enantiomerically chiral dinuclear zinc complexes with Schiff-base ligands, [Zn-2(R-L-1)(3)](ClO4)center dot H2O (1) and [Zn-2(S-L-1)(3)](ClO4)center dot H2O (2), [Zn-2(R-L-2)(3)](ClO4) (3) and [Zn-2(S-L-2)(3)](ClO4) (4) (R-L-1 or S-L-1 = R- or S-3-methoxy-6-(((methyl-2-pyridinylmethyl) imino)methyl)-Phenol. R-L-2 or S-L-2 = R- or S-1-((1-(pyridin-2-yl) ethylimino)methyl) naphthalen-2-ol), were synthesized and characterized. The strong solid-state fluorescence emissions were observed at around 490 nm for 1 and 2 and 580 nm for 3 and 4 at room temperature, respectively, which are attributed to the intraligand charge-transfer excite state. The fluorescence emissions of 3 and 4 exhibit obvious red-shift relative to 1 and 2. (C) 2012 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000305665800070 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/47473] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wen, He-Rui |
作者单位 | 1.Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Wen, He-Rui,Wang, Ying,Chen, Jing-Lin,et al. Syntheses, structures and properties of chiral dinuclear zinc complexes with Schiff-base ligands[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2012,20:303-306. |
APA | Wen, He-Rui,Wang, Ying,Chen, Jing-Lin,Tang, Yun-Zhi,Liao, Jin-Sheng,&Liu, Cai-Ming.(2012).Syntheses, structures and properties of chiral dinuclear zinc complexes with Schiff-base ligands.INORGANIC CHEMISTRY COMMUNICATIONS,20,303-306. |
MLA | Wen, He-Rui,et al."Syntheses, structures and properties of chiral dinuclear zinc complexes with Schiff-base ligands".INORGANIC CHEMISTRY COMMUNICATIONS 20(2012):303-306. |
入库方式: OAI收割
来源:化学研究所
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