中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Syntheses, structures and properties of chiral dinuclear zinc complexes with Schiff-base ligands

文献类型:期刊论文

作者Wen, He-Rui1; Wang, Ying1; Chen, Jing-Lin1; Tang, Yun-Zhi1; Liao, Jin-Sheng1; Liu, Cai-Ming2
刊名INORGANIC CHEMISTRY COMMUNICATIONS
出版日期2012-06-01
卷号20页码:303-306
关键词Zinc Complexes Chiral Schiff-base Crystal Structure Circular Dichroism Spectrum Luminescence Properties
ISSN号1387-7003
DOI10.1016/j.inoche.2012.03.036
英文摘要Two couples of enantiomerically chiral dinuclear zinc complexes with Schiff-base ligands, [Zn-2(R-L-1)(3)](ClO4)center dot H2O (1) and [Zn-2(S-L-1)(3)](ClO4)center dot H2O (2), [Zn-2(R-L-2)(3)](ClO4) (3) and [Zn-2(S-L-2)(3)](ClO4) (4) (R-L-1 or S-L-1 = R- or S-3-methoxy-6-(((methyl-2-pyridinylmethyl) imino)methyl)-Phenol. R-L-2 or S-L-2 = R- or S-1-((1-(pyridin-2-yl) ethylimino)methyl) naphthalen-2-ol), were synthesized and characterized. The strong solid-state fluorescence emissions were observed at around 490 nm for 1 and 2 and 580 nm for 3 and 4 at room temperature, respectively, which are attributed to the intraligand charge-transfer excite state. The fluorescence emissions of 3 and 4 exhibit obvious red-shift relative to 1 and 2. (C) 2012 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000305665800070
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/47473]  
专题中国科学院化学研究所
通讯作者Wen, He-Rui
作者单位1.Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Wen, He-Rui,Wang, Ying,Chen, Jing-Lin,et al. Syntheses, structures and properties of chiral dinuclear zinc complexes with Schiff-base ligands[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2012,20:303-306.
APA Wen, He-Rui,Wang, Ying,Chen, Jing-Lin,Tang, Yun-Zhi,Liao, Jin-Sheng,&Liu, Cai-Ming.(2012).Syntheses, structures and properties of chiral dinuclear zinc complexes with Schiff-base ligands.INORGANIC CHEMISTRY COMMUNICATIONS,20,303-306.
MLA Wen, He-Rui,et al."Syntheses, structures and properties of chiral dinuclear zinc complexes with Schiff-base ligands".INORGANIC CHEMISTRY COMMUNICATIONS 20(2012):303-306.

入库方式: OAI收割

来源:化学研究所

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