Preparation and characterization of poly(glycidyl methacrylate) grafted from magnesium hydroxide particles via SI-ATRP
文献类型：期刊论文
| 作者 | Liu, Jianhui1; Feng, Na1; Chang, Suqin2; Kang, Hongliang3 |
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2012-06-01 |
| 卷号 | 258期号:16页码:6127-6135 |
| 关键词 | Surface Modification Atrp Magnesium Hydroxide Particles Grafting From Polymers |
| ISSN号 | 0169-4332 |
| DOI | 10.1016/j.apsusc.2012.03.017 |
| 英文摘要 | In order to improve the compatibility of magnesium hydroxide particles [Mg(OH)(2)] and polymer matrix, poly(glycidyl methacrylate) (PGMA) grafted from magnesium hydroxide particles were synthesized via surface-initiated atom transfer radical polymerization (SI-ATRP). In this work, two approaches for the immobilization of ATRP initiator on the magnesium hydroxide particles surface were compared and selected. The density of initiator was significantly increased by the method of introducing more hydroxyl groups via ATRP of 2-hydroxyethyl methacrylate (HEMA) on the surface. The percentage of bromine atom for the initiator-functionalized magnesium hydroxide particles [Mg(OH)(2)-g-PHEMA-Br] reached to 1.75%, compared to 0.48% for Mg(OH)(2)-Br determined by XPS analysis. The surface-initiated ATRP of glycidyl methacrylate (GMA) can be conducted in a controlled manner, as revealed by the linear kinetic plot, linear increase of number average molecular weight (M-n) with monomer conversions, and the relatively narrow molecular weight distributions (M-w/M-n similar to 1.4) of PGMA chains. The percentage of grafting PG (%) and the thickness of the grafted polymer layer increased with the increasing of polymerization time and reached to 116.6% and 197.6 nm after 300 min respectively. As for the polymerization with different initial monomer concentration, the number average molecular weights (M-n) and weight average molecular weights (M-w) of PGMA increased with the increasing of initial monomer concentration. TGA indicated that the initial decomposition temperature of Mg(OH)(2)-g-PHEMA-PGMA composite particles (253 degrees C) was much lower than that of unmodified magnesium hydroxide particles (337 degrees C). (C) 2012 Elsevier B. V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000302784200034 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47513]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Feng, Na |
| 作者单位 | 1.Dalian Polytech Univ, Sch Text & Mat Engn, Dalian 116034, Peoples R China 2.China Leather & Footwear Ind Res Inst, Beijing 100015, Peoples R China 3.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Joint Lab Polymer Sci & Mat, Inst Chem,BNLMS, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Jianhui,Feng, Na,Chang, Suqin,et al. Preparation and characterization of poly(glycidyl methacrylate) grafted from magnesium hydroxide particles via SI-ATRP[J]. APPLIED SURFACE SCIENCE,2012,258(16):6127-6135. |
| APA | Liu, Jianhui,Feng, Na,Chang, Suqin,&Kang, Hongliang.(2012).Preparation and characterization of poly(glycidyl methacrylate) grafted from magnesium hydroxide particles via SI-ATRP.APPLIED SURFACE SCIENCE,258(16),6127-6135. |
| MLA | Liu, Jianhui,et al."Preparation and characterization of poly(glycidyl methacrylate) grafted from magnesium hydroxide particles via SI-ATRP".APPLIED SURFACE SCIENCE 258.16(2012):6127-6135. |
入库方式： OAI收割
来源：化学研究所
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