Block and Hetero Ethyl Cellulose Graft Copolymers Synthesized via Sequent and One-pot ATRP and "Click" Reactions
文献类型：期刊论文
| 作者 | Li Qinmei1,2; Kang Hongliang1; Liu Ruigang1; Huang Yong1,3 |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2012-09-01 |
| 卷号 | 30期号:9页码:2169-2175 |
| 关键词 | Ethyl Cellulose Graft Copolymers Atomic Transfer Radical Polymerization (Atrp) Click Reaction |
| ISSN号 | 1001-604X |
| DOI | 10.1002/cjoc.201200658 |
| 英文摘要 | Ethyl cellulose graft copolymers with block and hetero side chains, ethyl cellulose graft [polystyrene-b-poly(ethylene glycol)] [EC-g-(PS-b-PEG)] and ethyl cellulose graft polystyrene and polyethylene glycol [EC-g-(PS-PEG )] were synthesized by atomic transfer radical polymerization (ATRP) and alkyne-azide "click" reactions and "one-pot" ATRP and "click" reactions, respectively. For the synthesis of EC-g-(PS-b-PEG), the macroinitiator for ATRP was first synthesized via the esterification of hydroxyl groups of EC with 2-bromoisobutyryl bromide to result ethyl cellulose 2-bromoisobutyryl ester (EC-Br). The degree of substitution of bromide groups, which determined the graft density, can be tailored by varying the feeding ratios of the hydroxyl groups to 2-bromoisobutyryl bromide. Then ATRP was carried out for preparing EC-g-PS-Br with well-defined length of PS chains. The EC-g-PS-Br copolymers were then converted to EC-g-PS-N3 and then reacted with end alkyne-functionalized PEG via click to result in EC-g-(PS-b-PEG). The EC-g-(PS-PEG) copolymers were synthesized by converting bromide groups of EC-Br to azide groups (EC-Br-N3) and then by one-pot ATRP and "click" reactions. The resultant graft copolymers were characterized by FTIR and 1H NMR. The results indicate the success of the synthetic procedure of the cellulose graft copolymers with block and hetero side chains. |
| 语种 | 英语 |
| WOS记录号 | WOS:000309400700041 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47539]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu Ruigang |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Tech Inst Phys & Chem, Natl Engn Res Ctr Plast, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Qinmei,Kang Hongliang,Liu Ruigang,et al. Block and Hetero Ethyl Cellulose Graft Copolymers Synthesized via Sequent and One-pot ATRP and "Click" Reactions[J]. CHINESE JOURNAL OF CHEMISTRY,2012,30(9):2169-2175. |
| APA | Li Qinmei,Kang Hongliang,Liu Ruigang,&Huang Yong.(2012).Block and Hetero Ethyl Cellulose Graft Copolymers Synthesized via Sequent and One-pot ATRP and "Click" Reactions.CHINESE JOURNAL OF CHEMISTRY,30(9),2169-2175. |
| MLA | Li Qinmei,et al."Block and Hetero Ethyl Cellulose Graft Copolymers Synthesized via Sequent and One-pot ATRP and "Click" Reactions".CHINESE JOURNAL OF CHEMISTRY 30.9(2012):2169-2175. |
入库方式： OAI收割
来源：化学研究所
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