Sm@C-2v(3)-C-80: site-hopping motion of endohedral Sm atom and metal-induced effect on redox profile
文献类型：期刊论文
| 作者 | Xu, Wei3; Niu, Ben3,4; Shi, Zujin3; Lian, Yongfu4; Feng, Lai1,2 |
| 刊名 | NANOSCALE
 |
| 出版日期 | 2012-11-07 |
| 卷号 | 4期号:21页码:6876-6879 |
| ISSN号 | 2040-3364 |
| DOI | 10.1039/c2nr32193a |
| 英文摘要 | A new metallofullerene Sm@C-2v(3)-C-80 was synthesized and characterized. X-Ray analysis showed that the endohedral Sm atom undergoes a hopping motion between several off-center sites, even at low temperature. In addition, a comparative electrochemical study between Sm@C-2v(3)-C-80 and Yb@C-2v(3)-C-80 revealed their different redox potentials, suggesting a metal-induced effect on their redox profiles. |
| 语种 | 英语 |
| WOS记录号 | WOS:000310940500031 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47599]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shi, Zujin |
| 作者单位 | 1.Soochow Univ, Jiangsu Key Lab Thin Films, Suzhou 215006, Peoples R China 2.Soochow Univ, Sch Energy, Suzhou 215006, Peoples R China 3.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 4.Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Wei,Niu, Ben,Shi, Zujin,et al. Sm@C-2v(3)-C-80: site-hopping motion of endohedral Sm atom and metal-induced effect on redox profile[J]. NANOSCALE,2012,4(21):6876-6879. |
| APA | Xu, Wei,Niu, Ben,Shi, Zujin,Lian, Yongfu,&Feng, Lai.(2012).Sm@C-2v(3)-C-80: site-hopping motion of endohedral Sm atom and metal-induced effect on redox profile.NANOSCALE,4(21),6876-6879. |
| MLA | Xu, Wei,et al."Sm@C-2v(3)-C-80: site-hopping motion of endohedral Sm atom and metal-induced effect on redox profile".NANOSCALE 4.21(2012):6876-6879. |
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来源：化学研究所
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