Syntheses and second-order nonlinear optical properties of a series of new "H"-shape polymers
文献类型:期刊论文
作者 | Li, Zhong'an1; Qiu, Guofu2; Ye, Cheng3; Qin, Jingui1; Li, Zhen1 |
刊名 | DYES AND PIGMENTS |
出版日期 | 2012-07-01 |
卷号 | 94期号:1页码:16-22 |
ISSN号 | 0143-7208 |
关键词 | Click Chemistry H-type Chromophore Nonlinear Optics Synthesis Suzuki Coupling Copolymerization Suitable Isolation Group |
DOI | 10.1016/j.dyepig.2011.10.001 |
英文摘要 | To develop more "H"-shape nonlinear optical polymers, in this paper, four new polymers embedded with "H"-type chromophore moieties were designed and synthesized through a Suzuki coupling copolymerization reaction. The "H"-type chromophores were easily prepared by the utilization of "Click Chemistry" reactions, and their structures could be conveniently adjusted by changing the diazido groups. All the polymers exhibited good film-forming ability, thermal stability, and large optical nonlinearities. As a typical example, P4 demonstrated the highest d(33) value of 94.7 pm/V, and its onset temperature for decay was up to 103 degrees C, making it promising candidate for practical applications in photonic fields. (C) 2011 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
出版者 | ELSEVIER SCI LTD |
WOS记录号 | WOS:000301166600003 |
源URL | [http://ir.iccas.ac.cn/handle/121111/47637] |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, Zhen |
作者单位 | 1.Wuhan Univ, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China 2.Wuhan Univ, Coll Pharm, Wuhan 430072, Peoples R China 3.Chinese Acad Sci, Inst Chem, Organ Solids Labs, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Zhong'an,Qiu, Guofu,Ye, Cheng,et al. Syntheses and second-order nonlinear optical properties of a series of new "H"-shape polymers[J]. DYES AND PIGMENTS,2012,94(1):16-22. |
APA | Li, Zhong'an,Qiu, Guofu,Ye, Cheng,Qin, Jingui,&Li, Zhen.(2012).Syntheses and second-order nonlinear optical properties of a series of new "H"-shape polymers.DYES AND PIGMENTS,94(1),16-22. |
MLA | Li, Zhong'an,et al."Syntheses and second-order nonlinear optical properties of a series of new "H"-shape polymers".DYES AND PIGMENTS 94.1(2012):16-22. |
入库方式: OAI收割
来源:化学研究所
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