Radical self-assembled monolayers on Au(111) formed by the adsorption of closed-shell molecules
文献类型：期刊论文
| 作者 | Rissner, Ferdinand1; Ma, ZhongYun2,3; Hofmann, Oliver T.1; Slugovc, Christian4; Shuai, Zhigang5; Zojer, Egbert1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 22期号:10页码:4269-4272 |
| ISSN号 | 0959-9428 |
| DOI | 10.1039/c2jm15056e |
| 英文摘要 | Using density-functional theory band-structure calculations, we show how the exothermic adsorption of conjugated closed-shell organic semiconductor molecules on an Au(111) surface can turn them into radicals. For this to happen, we suggest the use of a thiocarbonyl docking group instead of the commonly applied thiols. The radicalisation of the adsorbed molecules resulting from the formation of the Au-S bond leads to reduced electron-and hole-injection barriers. The calculations predict two energetically close solutions for the adsorbed monolayer, one being non-magnetic and metallic and another being magnetic with reduced density of states at the Fermi energy. |
| 语种 | 英语 |
| WOS记录号 | WOS:000300250200014 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47645]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zojer, Egbert |
| 作者单位 | 1.Graz Univ Technol, Inst Solid State Phys, A-8010 Graz, Austria 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, Inst Chem, Key Lab Organ Solids, Beijing 100190, Peoples R China 3.Natl Univ Def Technol, Sch Aerosp & Mat Engn, Changsha 410073, Hunan, Peoples R China 4.Graz Univ Technol, Inst Chem & Technol Mat ICTM, A-8010 Graz, Austria 5.Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Rissner, Ferdinand,Ma, ZhongYun,Hofmann, Oliver T.,et al. Radical self-assembled monolayers on Au(111) formed by the adsorption of closed-shell molecules[J]. JOURNAL OF MATERIALS CHEMISTRY,2012,22(10):4269-4272. |
| APA | Rissner, Ferdinand,Ma, ZhongYun,Hofmann, Oliver T.,Slugovc, Christian,Shuai, Zhigang,&Zojer, Egbert.(2012).Radical self-assembled monolayers on Au(111) formed by the adsorption of closed-shell molecules.JOURNAL OF MATERIALS CHEMISTRY,22(10),4269-4272. |
| MLA | Rissner, Ferdinand,et al."Radical self-assembled monolayers on Au(111) formed by the adsorption of closed-shell molecules".JOURNAL OF MATERIALS CHEMISTRY 22.10(2012):4269-4272. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。