中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
One-pot solvothermal method to synthesize platinum/W18O49 ultrafine nanowires and their catalytic performance

文献类型:期刊论文

作者Zhang, Hongye; Huang, Changliang; Tao, Ranting; Zhao, Yanfei; Chen, Sha; Sun, Zhenyu; Liu, Zhimin
刊名JOURNAL OF MATERIALS CHEMISTRY
出版日期2012
卷号22期号:8页码:3354-3359
ISSN号0959-9428
DOI10.1039/c1jm15726d
英文摘要A simple solvothermal method was developed to prepare platinum/W18O49 ultrafine nanowires (<5 nm in diameter) through hydrolysis of WCl6 in ethanol-water solution in the presence of poly(N-vinyl-2-pyrrolidone) capping with Pt nanoparticles, and a series of Pt/W18O49 nanocomposites were obtained. These Pt/W18O49 composites were characterized by transmission electron microscopy, X-ray diffraction, Fourier-transform infrared spectra, X-ray photoelectron spectroscopy, and photoluminescence spectroscopy. It was demonstrated that PVP not only directed the formation of W18O49 nanowires, but also transferred the metal particles onto the oxide support without any size change. Due to the relatively strong interaction between Pt nanoparticles and the W18O49 nanowires, the as-prepared Pt/W18O49 composites exhibited blue shift in UV emission compared to the W18O49 nanowires, and displayed high activity and excellent stability for hydrogenation of p-chloronitrobenzene to p-chloroaniline with a selectivity of 99.7%.
语种英语
WOS记录号WOS:000299695400014
出版者ROYAL SOC CHEMISTRY
源URL[http://ir.iccas.ac.cn/handle/121111/47659]  
专题中国科学院化学研究所
通讯作者Liu, Zhimin
作者单位Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Hongye,Huang, Changliang,Tao, Ranting,et al. One-pot solvothermal method to synthesize platinum/W18O49 ultrafine nanowires and their catalytic performance[J]. JOURNAL OF MATERIALS CHEMISTRY,2012,22(8):3354-3359.
APA Zhang, Hongye.,Huang, Changliang.,Tao, Ranting.,Zhao, Yanfei.,Chen, Sha.,...&Liu, Zhimin.(2012).One-pot solvothermal method to synthesize platinum/W18O49 ultrafine nanowires and their catalytic performance.JOURNAL OF MATERIALS CHEMISTRY,22(8),3354-3359.
MLA Zhang, Hongye,et al."One-pot solvothermal method to synthesize platinum/W18O49 ultrafine nanowires and their catalytic performance".JOURNAL OF MATERIALS CHEMISTRY 22.8(2012):3354-3359.

入库方式: OAI收割

来源:化学研究所

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