中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The influence of residue aggregation in solution on photoluminescence and electroluminescence of polyoctylfluorene thin film

文献类型:期刊论文

作者Chen, Xi1,2; Wan, He1,2; Li, Haidong2; Cheng, Fengmei2; Nie, Wei1; Yao, Bing1; Xie, Zhiyuan1; Wang, Lixiang1; Zhang, Jidong1
刊名ORGANIC ELECTRONICS
出版日期2012-03-01
卷号13期号:3页码:475-482
关键词Polyoctylfluorene Residue Aggregation Luminescence
ISSN号1566-1199
DOI10.1016/j.orgel.2011.12.006
英文摘要PFO thin films made of toluene solution dissolved for 12, 30 and 80 min at 55 degrees C were prepared and then treated by solvent vapor annealing or thermal annealing. Their absorption, photoluminescence, electroluminescence and morphology were characterized. The results show that the thin film made of solution dissolved for short time contains trace beta phase PFO that lead to unusual emission. After solvent vapor annealing or thermal annealing, luminescence of such thin film is lower than that made of solution dissolved for long time. The surface morphology shows that such thin film contains large aggregations with size of 120 x 80 nm, which is in line with the light scattering results of 120 nm large particles in the solution, indicating the difference of luminescence originate from the residue aggregations. Such aggregations will lead to stronger diffraction peak in the in-plane GIXRD and weaker diffraction peak in the out-of-plane GIXRD, which indicates they have more ordered structure in main chain direction that will hinder the formation of ordered packing of PFO molecular chains in out-of-plane direction. These results demonstrate that the PFO solution needs to be dissolved for enough time to realize repeatment of high quality light-emitting device for actual massive application. (C) 2012 Elsevier B. V. All rights reserved.
语种英语
WOS记录号WOS:000300392100018
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/47681]  
专题中国科学院化学研究所
通讯作者Zhang, Jidong
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Changchun Univ Technol, Sch Chem Engn, Changchun 130012, Peoples R China
推荐引用方式
GB/T 7714
Chen, Xi,Wan, He,Li, Haidong,et al. The influence of residue aggregation in solution on photoluminescence and electroluminescence of polyoctylfluorene thin film[J]. ORGANIC ELECTRONICS,2012,13(3):475-482.
APA Chen, Xi.,Wan, He.,Li, Haidong.,Cheng, Fengmei.,Nie, Wei.,...&Zhang, Jidong.(2012).The influence of residue aggregation in solution on photoluminescence and electroluminescence of polyoctylfluorene thin film.ORGANIC ELECTRONICS,13(3),475-482.
MLA Chen, Xi,et al."The influence of residue aggregation in solution on photoluminescence and electroluminescence of polyoctylfluorene thin film".ORGANIC ELECTRONICS 13.3(2012):475-482.

入库方式: OAI收割

来源:化学研究所

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