Ionic liquid-stabilized graphene and its use in immobilizing a metal nanocatalyst
文献类型：期刊论文
| 作者 | Xiao, Wenjing; Sun, Zhenyu; Chen, Sha; Zhang, Hongye; Zhao, Yanfei; Huang, Changliang; Liu, Zhimin |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2012 |
| 卷号 | 2期号:21页码:8189-8193 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c2ra20774e |
| 英文摘要 | A new ionic liquid (IL), 1-butyl-3-methylimidazolium cholate, was first synthesized through an ion exchange reaction of 1-butyl-3-methylimidazolium chloride with sodium cholate. Stable aqueous dispersions of graphene were achieved by exfoliating graphite in the presence of the IL under ultrasonication. Both transmission electron microscopy and Raman measurements showed that the IL-stabilized graphene (IL-G) sheets existed with only a few (<5) layers. Furthermore, the IL-G was used to immobilize noble metal nanoparticles (Pt, Pd, Ru, Rh, etc), and a series of graphene-metal (G-M) composites with metal size <= 2 nm and very narrow size distributions were obtained. The resulting G-M exhibited superior catalytic performance with respect to hydrogenation of arenes. In particular, the as-prepared G-Ru with Ru content of 5% was very active for the hydrogenation of benzene to hexane with a turnover frequency as high as 6000 h(-1). The catalysts could be reused without detectable loss of activity, a result of their stable structure. |
| 语种 | 英语 |
| WOS记录号 | WOS:000307792200037 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47719]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xiao, Wenjing |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Wenjing,Sun, Zhenyu,Chen, Sha,et al. Ionic liquid-stabilized graphene and its use in immobilizing a metal nanocatalyst[J]. RSC ADVANCES,2012,2(21):8189-8193. |
| APA | Xiao, Wenjing.,Sun, Zhenyu.,Chen, Sha.,Zhang, Hongye.,Zhao, Yanfei.,...&Liu, Zhimin.(2012).Ionic liquid-stabilized graphene and its use in immobilizing a metal nanocatalyst.RSC ADVANCES,2(21),8189-8193. |
| MLA | Xiao, Wenjing,et al."Ionic liquid-stabilized graphene and its use in immobilizing a metal nanocatalyst".RSC ADVANCES 2.21(2012):8189-8193. |
入库方式： OAI收割
来源：化学研究所
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