Aggregate Transitions in Aqueous Solutions of Sodium Dodecylsulfate with a "Gemini-Type" Organic Salt
文献类型：期刊论文
| 作者 | Yu, Defeng1; Tian, Maozhang1; Fan, Yaxun1; Ji, Gang2; Wang, Yilin1 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2012-06-07 |
| 卷号 | 116期号:22页码:6425-6430 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp211431g |
| 英文摘要 | Effects of a "gemini-type" organic salt 1,2-bis(2-benzylammoniumethoxy) ethane dichloride (BEO) on the aggregation behavior of sodium dodecylsulfate (SDS) have been investigated by turbidity, surface tension, isothermal titration microcalorimetry, dynamic light scattering, cryogenic transmission electron microscopy, H-1 NMR spectroscopy, and differential scanning microcalorimetry. The aggregation behavior of the SDS/BEO mixed aqueous solution shows strong concentration and ratio dependence. For the SDS/BEO solution with a molar ratio of 5:1, large loose irregular aggregates, vesicles, and long thread-like micelles are formed in succession with the increase of the total SDS and BEO concentration. Because BEO has two positive charges, the SDS/BEO solution may consist of the (SDS)(2)-BEO gemini-type complex, the SDS-BEO complex and extra SDS. The aggregation ability and surface activity of the SDS/BEO mixture exhibit the characteristics of gemini-type surfactants. Along with the results of DSC and H-1 NMR, the (SDS)(2)-BEO gemini-type structure is confirmed to exist in the system. This work provides an approach to construct the surfactant systems with the characteristics of gemini surfactants through intermolecular interaction between a two-charged organic salt and oppositely charged single-chain surfactants. |
| 语种 | 英语 |
| WOS记录号 | WOS:000304888600021 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47739]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Yilin |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Colloid & Interface Sci, BNLMS, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Ctr Biol Electron Microscopy, Inst Biophys, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Defeng,Tian, Maozhang,Fan, Yaxun,et al. Aggregate Transitions in Aqueous Solutions of Sodium Dodecylsulfate with a "Gemini-Type" Organic Salt[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2012,116(22):6425-6430. |
| APA | Yu, Defeng,Tian, Maozhang,Fan, Yaxun,Ji, Gang,&Wang, Yilin.(2012).Aggregate Transitions in Aqueous Solutions of Sodium Dodecylsulfate with a "Gemini-Type" Organic Salt.JOURNAL OF PHYSICAL CHEMISTRY B,116(22),6425-6430. |
| MLA | Yu, Defeng,et al."Aggregate Transitions in Aqueous Solutions of Sodium Dodecylsulfate with a "Gemini-Type" Organic Salt".JOURNAL OF PHYSICAL CHEMISTRY B 116.22(2012):6425-6430. |
入库方式： OAI收割
来源：化学研究所
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