Effect of Grain Size on Pressure-Induced Structural Transition in Mn3O4
文献类型：期刊论文
| 作者 | Lv, Hang1; Yao, Mingguang1; Li, Quanjun1; Li, Zepeng1,5; Liu, Bo1; Liu, Ran1; Lu, Shuangchen1; Li, Dongmei1; Mao, Jun2; Ji, Xiangling2 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2012-01-26 |
| 卷号 | 116期号:3页码:2165-2171 |
| ISSN号 | 1932-7447 |
| DOI | 10.1021/jp2067028 |
| 英文摘要 | The size effect on structural transitions of Mn3O4 has been investigated under pressures by in situ synchrotron X-ray diffraction and Raman technique in a diamond anvil cell. Compared with bulk Mn3O4, Mn3O4 nanoparticles show an obvious elevation of phase transition pressure and different phase transformation routines with the occurrence of a new high-pressure phase at 14.5-23.5 GPa. The new phase most probably has an orthorhombic CaTi2O4-type structure, which is regarded as a metastable phase transforming to the higher pressure marokite-like structure. By the return to ambient pressure, the marokite phase is quenchable in bulk Mn3O4, whereas the coexistence of hausmannite and marokite phase is observed in the recovered Mn3O4 nanoparticles. It is proposed that the unique atomic conformation in Mn3O4 spinel structures, the cation distribution, and the higher surface energy together with the size-induced effect of nanocrystalline Mn3O4 probably play crucial roles in the high-pressure behavior of Mn3O4 nanoparticles. |
| 语种 | 英语 |
| WOS记录号 | WOS:000299584400016 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47829]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Bingbing |
| 作者单位 | 1.Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China 2.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun Inst Appl Chem, Changchun 130012, Peoples R China 3.Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Inst High Energy Phys, Beijing 100049, Peoples R China 4.SUNY Stony Brook, GeoSci Dept, Stony Brook, NY 11794 USA 5.Civil Aviat Univ China, Coll Sci, Tianjin 300300, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, Hang,Yao, Mingguang,Li, Quanjun,et al. Effect of Grain Size on Pressure-Induced Structural Transition in Mn3O4[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2012,116(3):2165-2171. |
| APA | Lv, Hang.,Yao, Mingguang.,Li, Quanjun.,Li, Zepeng.,Liu, Bo.,...&Liu, Bingbing.(2012).Effect of Grain Size on Pressure-Induced Structural Transition in Mn3O4.JOURNAL OF PHYSICAL CHEMISTRY C,116(3),2165-2171. |
| MLA | Lv, Hang,et al."Effect of Grain Size on Pressure-Induced Structural Transition in Mn3O4".JOURNAL OF PHYSICAL CHEMISTRY C 116.3(2012):2165-2171. |
入库方式： OAI收割
来源：化学研究所
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