Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties
文献类型:期刊论文
作者 | Wang XinYi1; Wang ZheMing2; Gao Song2 |
刊名 | SCIENCE CHINA-CHEMISTRY
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出版日期 | 2012-06-01 |
卷号 | 55期号:6页码:1055-1063 |
关键词 | Metal Formate Spin-flop Magnetic Phase Diagram Photodimerization |
ISSN号 | 1674-7291 |
DOI | 10.1007/s11426-012-4561-6 |
英文摘要 | Detailed studies of the structures, magnetic properties and photodimerization of a series of formato-bridged MOFs with the general formula M-2(HCOO)(3)(4,4'-bpe)(3)(H2O)(3)(X) (4,4'-bpe = 4,4'-bipyridylethylene, M = Mn (1-X-), X- = ClO (4) (-) , NO (3) (-) , BF (4) (-) , I-, Br-; M = Co (2 (-)-X-), X- = ClO (4) (-) , NO (3) (-) ; M = Zn (3-X-), X- = NO3/-) were reported. Careful magnetic measurements on an oriented single crystal of 1-ClO (4) (-) determined the spin-flop magnetic phase diagram and some intrinsic parameters, such as the intralayer coupling J, the anisotropy field H (A) and the exchange field H (E). Different anions can remarkably tune the magnetic properties of 1-X-, especially the critical fields of the spin-flop transition. Compound 2-ClO (4) (-) remained paramagnetic down to 2 K. |
语种 | 英语 |
WOS记录号 | WOS:000305238400026 |
出版者 | SCIENCE PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/47833] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang XinYi |
作者单位 | 1.Nanjing Univ, Sch Chem & Chem Engn, Nanjing Natl Lab Microstruct, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Wang XinYi,Wang ZheMing,Gao Song. Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties[J]. SCIENCE CHINA-CHEMISTRY,2012,55(6):1055-1063. |
APA | Wang XinYi,Wang ZheMing,&Gao Song.(2012).Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties.SCIENCE CHINA-CHEMISTRY,55(6),1055-1063. |
MLA | Wang XinYi,et al."Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties".SCIENCE CHINA-CHEMISTRY 55.6(2012):1055-1063. |
入库方式: OAI收割
来源:化学研究所
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