中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties

文献类型:期刊论文

作者Wang XinYi1; Wang ZheMing2; Gao Song2
刊名SCIENCE CHINA-CHEMISTRY
出版日期2012-06-01
卷号55期号:6页码:1055-1063
关键词Metal Formate Spin-flop Magnetic Phase Diagram Photodimerization
ISSN号1674-7291
DOI10.1007/s11426-012-4561-6
英文摘要Detailed studies of the structures, magnetic properties and photodimerization of a series of formato-bridged MOFs with the general formula M-2(HCOO)(3)(4,4'-bpe)(3)(H2O)(3)(X) (4,4'-bpe = 4,4'-bipyridylethylene, M = Mn (1-X-), X- = ClO (4) (-) , NO (3) (-) , BF (4) (-) , I-, Br-; M = Co (2 (-)-X-), X- = ClO (4) (-) , NO (3) (-) ; M = Zn (3-X-), X- = NO3/-) were reported. Careful magnetic measurements on an oriented single crystal of 1-ClO (4) (-) determined the spin-flop magnetic phase diagram and some intrinsic parameters, such as the intralayer coupling J, the anisotropy field H (A) and the exchange field H (E). Different anions can remarkably tune the magnetic properties of 1-X-, especially the critical fields of the spin-flop transition. Compound 2-ClO (4) (-) remained paramagnetic down to 2 K.
语种英语
WOS记录号WOS:000305238400026
出版者SCIENCE PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/47833]  
专题中国科学院化学研究所
通讯作者Wang XinYi
作者单位1.Nanjing Univ, Sch Chem & Chem Engn, Nanjing Natl Lab Microstruct, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Wang XinYi,Wang ZheMing,Gao Song. Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties[J]. SCIENCE CHINA-CHEMISTRY,2012,55(6):1055-1063.
APA Wang XinYi,Wang ZheMing,&Gao Song.(2012).Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties.SCIENCE CHINA-CHEMISTRY,55(6),1055-1063.
MLA Wang XinYi,et al."Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties".SCIENCE CHINA-CHEMISTRY 55.6(2012):1055-1063.

入库方式: OAI收割

来源:化学研究所

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