Cellulose Benzoyl Ester with Different Substitution Degree Supported Ru Nano-clusters Catalyst for Benzene Hydrogenation
文献类型：期刊论文
| 作者 | Wang Lijuan1,2; Zhang Aiqing1,2; Li Lin1,2; Liu Hanfan1,2,3; Liu Shuzheng1,2 |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2012-04-28 |
| 卷号 | 70期号:8页码:1021-1027 |
| 关键词 | Ru Nano-cluster Cellulose Benzoyl Ester Benzene Cyclohexene Swelling |
| ISSN号 | 0567-7351 |
| 英文摘要 | Cellulose benzoyl ester (CB) was synthesized from cellulose and benzoyl chloride. Different substitution degree CBs were obtained by controlling the amount of benzoyl chloride, and the resulting CBs have different swelling degree in benzene, cyclohexene and cyclohexane. Hybrid membrane, which was used for the selective hydrogenation, was prepared by supporting Ru nano-clusters (obtained by refluxing reduction of RuCl3 with n-butyl alcohol) into CB. CBs and the hybrid membranes were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and transmission electron microscope (TEM), etc. Research results demonstrated that swelling behavior acts as a crucial factor to the selectivity of cyclohexene. Active evaluation results indicated that the conversion of benzene (highest, 2.8%) increased while the selectivity of cyclohexene (highest, 53.4%) decreased with the increasing of CBs substitution degree. |
| 语种 | 英语 |
| WOS记录号 | WOS:000304284400012 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47891]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang Lijuan |
| 作者单位 | 1.S Cent Univ Nationalities, Coll Chem & Mat Sci, State Ethn Affairs Commiss, Key Lab Catalysis & Mat Sci, Wuhan 430074, Peoples R China 2.S Cent Univ Nationalities, Coll Chem & Mat Sci, Minist Educ, Wuhan 430074, Peoples R China 3.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Lijuan,Zhang Aiqing,Li Lin,et al. Cellulose Benzoyl Ester with Different Substitution Degree Supported Ru Nano-clusters Catalyst for Benzene Hydrogenation[J]. ACTA CHIMICA SINICA,2012,70(8):1021-1027. |
| APA | Wang Lijuan,Zhang Aiqing,Li Lin,Liu Hanfan,&Liu Shuzheng.(2012).Cellulose Benzoyl Ester with Different Substitution Degree Supported Ru Nano-clusters Catalyst for Benzene Hydrogenation.ACTA CHIMICA SINICA,70(8),1021-1027. |
| MLA | Wang Lijuan,et al."Cellulose Benzoyl Ester with Different Substitution Degree Supported Ru Nano-clusters Catalyst for Benzene Hydrogenation".ACTA CHIMICA SINICA 70.8(2012):1021-1027. |
入库方式： OAI收割
来源：化学研究所
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