Rotamers of m-fluoroanisole studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy
文献类型：期刊论文
| 作者 | Shiung, Kui Shiu1,2; Yu, Dan1,3; Huang, Hsin Chang1; Tzeng, Wen Bih1,2 |
| 刊名 | JOURNAL OF MOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2012-04-01 |
| 卷号 | 274页码:43-47 |
| 关键词 | Cation Spectroscopy Cation Vibration Threshold Ionization Resonant Ionization M-fluoroanisole |
| ISSN号 | 0022-2852 |
| DOI | 10.1016/j.jms.2012.04.004 |
| 英文摘要 | We report the cation spectra of the cis and trans rotamers of m-fluoroanisole, recorded by using the two-color resonant two-photon mass-analyzed threshold ionization spectroscopic technique. The adiabatic ionization energies of the cis and trans rotamers are 67 867 +/- 5 and 68 304 +/- 5 cm(-1), respectively. The observed active vibrations 6b, 6a, 1, and 12 are found to have frequencies of 473, 549, 714, and 955 cm(-1) for the cis rotamer and 463, 565, 714, and 962 cm(-1) for the trans rotamer of m-fluoroanisole in the cationic ground state, respectively. These results show that the frequency depends on the nature, vibrational pattern, relative orientation and the extent of the F and OCH3 substituents participation in the normal vibration. (c) 2012 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000305052300008 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47943]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tzeng, Wen Bih |
| 作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 2.Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan 3.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shiung, Kui Shiu,Yu, Dan,Huang, Hsin Chang,et al. Rotamers of m-fluoroanisole studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy[J]. JOURNAL OF MOLECULAR SPECTROSCOPY,2012,274:43-47. |
| APA | Shiung, Kui Shiu,Yu, Dan,Huang, Hsin Chang,&Tzeng, Wen Bih.(2012).Rotamers of m-fluoroanisole studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy.JOURNAL OF MOLECULAR SPECTROSCOPY,274,43-47. |
| MLA | Shiung, Kui Shiu,et al."Rotamers of m-fluoroanisole studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy".JOURNAL OF MOLECULAR SPECTROSCOPY 274(2012):43-47. |
入库方式： OAI收割
来源：化学研究所
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