Water as an additive to enhance the ring opening of naphthalene
文献类型：期刊论文
| 作者 | Wang, Qian; Fan, Honglei; Wu, Suxiang; Zhang, Zhaofu; Zhang, Peng; Han, Buxing |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 14期号:4页码:1152-1158 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c2gc16554f |
| 英文摘要 | Use of water as a reaction medium or additive to enhance reaction efficiency is an important topic in green chemistry, and ring opening and contraction reactions of aromatics are crucial for upgrading diesels. In this work, we investigated the effect of water on the yields of ring opening and contraction reactions of naphthalene. A series of catalysts, such as Rh2O3/HY zeolite, Mo-Ni oxide and their physical mixtures, were used as the catalysts. The influences of the amount of water, hydrogen pressure, reaction temperature and reaction time on the yields of the ring opening and contraction products (ROCP) were studied. It was found that Rh2O3/HY and Mo-Ni oxide showed an excellent synergistic effect for catalyzing the reaction, and water could be used as a green and efficient additive for enhancing the yield of the ROCP. At the optimized conditions, the yield of the ROCP could be as high as 63.3%. The mechanism for the effect of water on the reactions was discussed on the basis of control experiments. |
| 语种 | 英语 |
| WOS记录号 | WOS:000302018600041 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47973]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Qian |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Qian,Fan, Honglei,Wu, Suxiang,et al. Water as an additive to enhance the ring opening of naphthalene[J]. GREEN CHEMISTRY,2012,14(4):1152-1158. |
| APA | Wang, Qian,Fan, Honglei,Wu, Suxiang,Zhang, Zhaofu,Zhang, Peng,&Han, Buxing.(2012).Water as an additive to enhance the ring opening of naphthalene.GREEN CHEMISTRY,14(4),1152-1158. |
| MLA | Wang, Qian,et al."Water as an additive to enhance the ring opening of naphthalene".GREEN CHEMISTRY 14.4(2012):1152-1158. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。