Neutral cuprous complexes as ratiometric oxygen gas sensors
文献类型：期刊论文
| 作者 | Liu, Xiaohui1,3; Sun, Wei1,3; Zou, Luyi1; Xie, Zhiyuan1; Li, Xiao1; Lu, Canzhong2; Wang, Lixiang1; Cheng, Yanxiang1 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2012 |
| 卷号 | 41期号:4页码:1312-1319 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c1dt11777g |
| 英文摘要 | Four neutral mononuclear Cu(I) complexes, [Cu(pyin)(PPh(3))(2)] (1a), [Cu(pyin)(DPEphos)] (1b), [Cu(quin)(PPh(3))(2)] (2a) and [Cu(quin)(DPEphos)] (2b) (Hpyin = 2-(2-pyridyl) indole, Hquin = 2-(2-quinolyl)indole and DPEphos = bis(2-(diphenylphosphino)phenyl)ether) have been synthesized. X-Ray crystal structure analysis revealed that the central Cu(I) ion in all complexes is in a distorted tetrahedral coordination environment. All four complexes display the typical metal-to-ligand charge transfer (MLCT) absorption band at 371, 363, 413 and 402 nm, respectively. No emission was observed from any complexes in the solid state due to triplet-triplet annihilation. However, the complexes show unusual dual-emission originating from intraligand charge-transfer (ILCT) and MLCT transitions, when dispersed in a rigid matrix (e. g. PMMA) or in frozen CH(2)Cl(2). The oxidation potential of Cu(I)/Cu(II) in these neutral complexes, similar to 0.5 V (vs. Ag/AgCl), is lower than those of cationic Cu(I) complexes. Films containing 10 wt% of these complexes in PMMA shows ratiometric fluorescent oxygen gas sensing property with a response ratio of 0.3-3.2 and response time of 3-4 s. Complex 2b acts as a ratiometric oxygen gas sensor with good reversibility through energy and electron transfer mechanisms under the loss of a counteranion. |
| 语种 | 英语 |
| WOS记录号 | WOS:000299054200029 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/47995]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Cheng, Yanxiang |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun Inst Appl Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiaohui,Sun, Wei,Zou, Luyi,et al. Neutral cuprous complexes as ratiometric oxygen gas sensors[J]. DALTON TRANSACTIONS,2012,41(4):1312-1319. |
| APA | Liu, Xiaohui.,Sun, Wei.,Zou, Luyi.,Xie, Zhiyuan.,Li, Xiao.,...&Cheng, Yanxiang.(2012).Neutral cuprous complexes as ratiometric oxygen gas sensors.DALTON TRANSACTIONS,41(4),1312-1319. |
| MLA | Liu, Xiaohui,et al."Neutral cuprous complexes as ratiometric oxygen gas sensors".DALTON TRANSACTIONS 41.4(2012):1312-1319. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。