Enantioselective oxysulfenylation and oxyselenenylation of olefins catalyzed by chiral Bronsted acids
文献类型：期刊论文
| 作者 | Guan, Huan1; Wang, Haining1; Huang, Deshun1; Shi, Yian1,2 |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2012-03-25 |
| 卷号 | 68期号:12页码:2728-2735 |
| 关键词 | Sulfenylation Selenenylation Thiiranium Ions Seleniranium Ions Desymmetrization Enantioselective |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2012.01.006 |
| 英文摘要 | This paper describes Bronsted acid catalyzed enantioselective oxysulfenylation and oxyselenenylation of olefins. Enantiomerically enriched tetrahydrofurans are formed with up to 63% ee with dibenzoyl-D-tartaric acid and its derivatives as catalyst. Chiral beta-carboxyl sulfides and selenides have also been obtained with up to 50% and 84% ee, respectively, via enantioselective desymmetrization of thiiranium and seleniranium ions in the presence of catalytic amounts of chiral binaphthol derived N-triflyl phosphoramide. (C) 2012 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000301692700021 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48107]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shi, Yian |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA |
| 推荐引用方式 GB/T 7714 | Guan, Huan,Wang, Haining,Huang, Deshun,et al. Enantioselective oxysulfenylation and oxyselenenylation of olefins catalyzed by chiral Bronsted acids[J]. TETRAHEDRON,2012,68(12):2728-2735. |
| APA | Guan, Huan,Wang, Haining,Huang, Deshun,&Shi, Yian.(2012).Enantioselective oxysulfenylation and oxyselenenylation of olefins catalyzed by chiral Bronsted acids.TETRAHEDRON,68(12),2728-2735. |
| MLA | Guan, Huan,et al."Enantioselective oxysulfenylation and oxyselenenylation of olefins catalyzed by chiral Bronsted acids".TETRAHEDRON 68.12(2012):2728-2735. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。