Thinning Segregated Graphene Layers on High Carbon Solubility Substrates of Rhodium Foils by Tuning the Quenching Process
文献类型：期刊论文
| 作者 | Liu, Mengxi1; Zhang, Yanfeng1,2; Chen, Yubin1; Gao, Yabo1; Gao, Teng1; Ma, Donglin1; Ji, Qingqing1; Zhang, Yu1,2; Li, Cong1; Liu, Zhongfan1 |
| 刊名 | ACS NANO
 |
| 出版日期 | 2012-12-01 |
| 卷号 | 6期号:12页码:10581-10589 |
| 关键词 | Graphene Apcvd Moire Pattern Stm Wrinkle |
| ISSN号 | 1936-0851 |
| DOI | 10.1021/nn3047154 |
| 英文摘要 | We report the synthesis of large-scale uniform graphene films on high carbon solubility substrates of Rh foils for the first time using an ambient-pressure chemical vapor deposition method. We find that, by increasing the cooling rate in the growth process, the thickness of graphene can be tuned from multilayer to monolayer, resulting from the different segregation amount of carbon atoms from bulk to surface. The growth feature was characterized with scanning electron microscopy, Raman spectra, transmission electron microscopy, and scanning tunneling microscopy. We also find that bilayer or few-layer graphene prefers to stack deviating from the Bernal stacking geometry, with the formation of versatile moire patterns. On the basis of these results, we put forward a segregation growth mechanism for graphene growth on Rh foils. Of particular importance, we propose that this randomly stacked few-layer graphene can be a model system for exploring some fantastic physical properties such as van Hove singularities. |
| 语种 | 英语 |
| WOS记录号 | WOS:000312563600018 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48113]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Yanfeng |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Ctr Nanochem CNC,Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Mengxi,Zhang, Yanfeng,Chen, Yubin,et al. Thinning Segregated Graphene Layers on High Carbon Solubility Substrates of Rhodium Foils by Tuning the Quenching Process[J]. ACS NANO,2012,6(12):10581-10589. |
| APA | Liu, Mengxi.,Zhang, Yanfeng.,Chen, Yubin.,Gao, Yabo.,Gao, Teng.,...&Liu, Zhongfan.(2012).Thinning Segregated Graphene Layers on High Carbon Solubility Substrates of Rhodium Foils by Tuning the Quenching Process.ACS NANO,6(12),10581-10589. |
| MLA | Liu, Mengxi,et al."Thinning Segregated Graphene Layers on High Carbon Solubility Substrates of Rhodium Foils by Tuning the Quenching Process".ACS NANO 6.12(2012):10581-10589. |
入库方式： OAI收割
来源：化学研究所
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