Synthesis and properties of polyimides based on isomeric (4, 4 '-methylenediphenoxyl) bis (phthalic anhydride)s (BPFDAs)
文献类型：期刊论文
| 作者 | Li, Yuan1; Wang, Zhen2; Li, Guijuan1; Ding, Mengxian2,3; Yan, Jingling2 |
| 刊名 | JOURNAL OF POLYMER RESEARCH
 |
| 出版日期 | 2012 |
| 卷号 | 19期号:1 |
| 关键词 | Bpfdas Isomeric Polyimides Synthesis Structure-property Relationship |
| ISSN号 | 1022-9760 |
| DOI | 10.1007/s10965-011-9772-6 |
| 英文摘要 | Isomeric (4, 4'-methylenediphenoxyl) bis (phthalic anhydride)s (BPFDAs) were synthesized and their structures were determined via IR spectra and H-1 NMR. Polyimides were then prepared from isomeric BPFDAs and aromatic diamines in N, N-Dimethylacetamide (DMAc) via the conventional two-step method. Polyimides based on 3, 3'-BPFDA are soluble in common organic solvents at room temperature, while polyimides based on 4, 4'-BPFDA were only partially soluble in high-boiling-point solvent even upon heating. The 5% weight-loss temperatures (T-5%) of these polyimides were in the range of 430-500 degrees C in air. Dynamic mechanical thermal analysis (DMTA) indicated that the glass-transition temperatures of polyimides from 3, 3'-BPFDA are around 10-20 degrees C higher than those of polyimides from 4, 4'-BPFDA. The wide-angle X-ray diffraction showed that all polyimides are amorphous. |
| 语种 | 英语 |
| WOS记录号 | WOS:000300772600021 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48151]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yan, Jingling |
| 作者单位 | 1.Changchun Univ Technol, Sch Chem Engn, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 3.Changchun Hipolyking Co Ltd, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yuan,Wang, Zhen,Li, Guijuan,et al. Synthesis and properties of polyimides based on isomeric (4, 4 '-methylenediphenoxyl) bis (phthalic anhydride)s (BPFDAs)[J]. JOURNAL OF POLYMER RESEARCH,2012,19(1). |
| APA | Li, Yuan,Wang, Zhen,Li, Guijuan,Ding, Mengxian,&Yan, Jingling.(2012).Synthesis and properties of polyimides based on isomeric (4, 4 '-methylenediphenoxyl) bis (phthalic anhydride)s (BPFDAs).JOURNAL OF POLYMER RESEARCH,19(1). |
| MLA | Li, Yuan,et al."Synthesis and properties of polyimides based on isomeric (4, 4 '-methylenediphenoxyl) bis (phthalic anhydride)s (BPFDAs)".JOURNAL OF POLYMER RESEARCH 19.1(2012). |
入库方式： OAI收割
来源：化学研究所
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