Rh(II)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides
文献类型：期刊论文
| 作者 | Li, Yuye1,2,3; Huang, Zhongxing2,3; Wu, Xinhu1,2,3; Xu, Peng-Fei1; Jin, Jing1; Zhang, Yan1,2,3; Wang, Jianbo2,3 |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2012-07-01 |
| 卷号 | 68期号:26页码:5234-5240 |
| 关键词 | Sulfur Ylides N-tosylhydrazone Allylic Phenyl Sulfides Propargyl Phenyl Sulfides [2 3]-sigmatropic Rearrangement |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2012.03.032 |
| 英文摘要 | In this paper, Rh-2(OAc)(4)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides is reported. A series of tosylhydrazones derived from aldehydes were successfully used for [2,3]-sigmatropic rearrangement by reaction with either allylic phenyl sulfides or propargyl phenyl sulfides. The reaction conditions were optimized and afforded the products in moderate to good yields. In addition, a novel and convenient approach for the synthesis of cyclobutenones and cyclopropanes has been developed through direct oxidation of the rearrangement products. (C) 2012 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000305381700019 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48213]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xu, Peng-Fei |
| 作者单位 | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Peking Univ, BNLMS, Coll Chem, Minist Educ, Beijing 100871, Peoples R China 3.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Minist Educ, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yuye,Huang, Zhongxing,Wu, Xinhu,et al. Rh(II)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides[J]. TETRAHEDRON,2012,68(26):5234-5240. |
| APA | Li, Yuye.,Huang, Zhongxing.,Wu, Xinhu.,Xu, Peng-Fei.,Jin, Jing.,...&Wang, Jianbo.(2012).Rh(II)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides.TETRAHEDRON,68(26),5234-5240. |
| MLA | Li, Yuye,et al."Rh(II)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides".TETRAHEDRON 68.26(2012):5234-5240. |
入库方式： OAI收割
来源：化学研究所
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