New main-chain hyperbranched polymers: Facile synthesis, structural control, and second-order nonlinear optical properties
文献类型：期刊论文
| 作者 | Li, Zhong'an1; Wu, Wenbo1; Ye, Cheng2; Qin, Jingui1; Li, Zhen1 |
| 刊名 | POLYMER
 |
| 出版日期 | 2012-01-05 |
| 卷号 | 53期号:1页码:153-160 |
| 关键词 | Nonlinear Optics Hyperbranched Polymer Suitable Isolation Groups |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2011.11.015 |
| 英文摘要 | In this paper, two new series of hyperbranched main-chain polymers, P1-P6, with chromophore moieties as the core were successfully prepared through "A(3)+B-2" approach via simple Sonogashira coupling reaction. By changing the bulky size of comonomers, the structure-property relationship has been investigated according to the concept of "suitable isolation group". The second harmonic generation (SHG) experiments demonstrated that the hyperbranched structure might be very good architecture for the development of NLO materials with high performance. The benzene ring (Bz) could act as suitable isolation groups in these polymers, while the d(33) values of the corresponding polymers P1 and P4, were 152.6 and 86.2 pm/V, respectively, much higher than their linear analog polymers bearing the same chromophore moieties. In addition, these hyperbranched main-chain polymers could combine the large nonlinearities of hyperbranched polymers and high stability of main-chain polymers, providing a new solution to solve the "nonlinearity-stability" trade off existing in the main-chain polymers to some degree. (C) 2011 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000300073600017 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48237]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Zhen |
| 作者单位 | 1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Inst Chem, Organ Solids Labs, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Zhong'an,Wu, Wenbo,Ye, Cheng,et al. New main-chain hyperbranched polymers: Facile synthesis, structural control, and second-order nonlinear optical properties[J]. POLYMER,2012,53(1):153-160. |
| APA | Li, Zhong'an,Wu, Wenbo,Ye, Cheng,Qin, Jingui,&Li, Zhen.(2012).New main-chain hyperbranched polymers: Facile synthesis, structural control, and second-order nonlinear optical properties.POLYMER,53(1),153-160. |
| MLA | Li, Zhong'an,et al."New main-chain hyperbranched polymers: Facile synthesis, structural control, and second-order nonlinear optical properties".POLYMER 53.1(2012):153-160. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。