FIELD DESORPTION MASS SPECTROMETRY CHARACTERIZATION FOR RELATIVE MOLECULAR MASS AND DISTRIBUTION OF PHENOLIC RESIN
文献类型：期刊论文
| 作者 | Wang Juan; Zhao Tong |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2012-02-20 |
| 期号 | 2页码:103-110 |
| 关键词 | Field Desorption Mass Spectrometry (Fd-ms) Phenolic Resin Cresol Novolac Resin Relative Molecular Mass And Distribution |
| ISSN号 | 1000-3304 |
| DOI | 10.3724/SP.J.1105.2012.11081 |
| 英文摘要 | The characterization of relative molecular mass and distribution of phenolic resins by modern analytical techniques is detailed. Common VPO, CC, HPLC and GPC methods are referenced. But these methods are restrictive in analysing the phenolic resins with more isomers. Field desorption (FD) is a term used to describe the formation of ions in the gas phase from a material deposited on a solid surface (known as an 'emitter') in the presence of a high electrical field. The field desorption mass spectrometry (FD-MS) of the phenolic resins can give the molecular ion peak and the content of the every phenol unit without fragment ion peaks. A series of phenolic resins was made with various raw materials. The phenol-formaldehyde resole resin, the phenol-formaldehyde novolac resin, the cresol-formaldehyde novolac resin and the phenol-cresol-formaldehyde novolac resin were determined by FD-MS. The sample concentration is 10 mg/mL, the heating current is 10 similar to 30 mA/min, the ionization voltage is 5 similar to 8 kV. The FD-MS shows us the molecular ion peak and the content of the every phenol unit without any fragment ion peaks. By FD-MS analysing we can also get the informations about the degree of polymerization, raw materials, characteristics and so on. So the FD-MS method is convenient and impactful for differentiating of the various phenolic resins,suitable for the characterization of relative molecular mass and distribution of the phenolic resin. |
| 语种 | 英语 |
| WOS记录号 | WOS:000301870400002 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48265]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang Juan |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Juan,Zhao Tong. FIELD DESORPTION MASS SPECTROMETRY CHARACTERIZATION FOR RELATIVE MOLECULAR MASS AND DISTRIBUTION OF PHENOLIC RESIN[J]. ACTA POLYMERICA SINICA,2012(2):103-110. |
| APA | Wang Juan,&Zhao Tong.(2012).FIELD DESORPTION MASS SPECTROMETRY CHARACTERIZATION FOR RELATIVE MOLECULAR MASS AND DISTRIBUTION OF PHENOLIC RESIN.ACTA POLYMERICA SINICA(2),103-110. |
| MLA | Wang Juan,et al."FIELD DESORPTION MASS SPECTROMETRY CHARACTERIZATION FOR RELATIVE MOLECULAR MASS AND DISTRIBUTION OF PHENOLIC RESIN".ACTA POLYMERICA SINICA .2(2012):103-110. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。