Sugar-metal ion interactions: the coordination behaviors of lanthanum with erythritol
文献类型：期刊论文
| 作者 | Xue, Junhui1,3; Hua, Xiaohui2; Li, Weihong2; Yang, Limin1; Xu, Yizhuang2; Zhao, Guozhong4; Zhang, Gaohui4; Li, Chunping3; Liu, Kexin1; Chen, Jia'er1 |
| 刊名 | CARBOHYDRATE RESEARCH
 |
| 出版日期 | 2012-11-01 |
| 卷号 | 361页码:12-18 |
| 关键词 | Lanthanum Ion Ftir Complexation Erythritol Crystal Structure |
| ISSN号 | 0008-6215 |
| DOI | 10.1016/j.carres.2012.07.026 |
| 英文摘要 | Three novel lanthanum chloride-erythritol complexes (LaCl3 center dot C4H10O4 center dot 5H(2)O (LaE(I)), LaCl3 center dot C4H10O4 center dot 3H(2)O (LaE(II)), and LaCl3 center dot 1.5C(4)H(10)O(4) (LaE(III)) were synthesized and characterized by single crystal X-ray diffraction, FTIR, far-IR, THz, and Raman spectroscopy. The coordination number of La3+ is nine. LaE(I) and LaE(II) have similar coordination spheres, but their hydrogen bond networks are different. Erythritol exhibits two coordination modes: two bidentate ligands and tridentate ligands in LaE(III). Chloride ions and water coordinate with La3+ or participate in the hydrogen-bond networks in the three complexes. Crystal structures, FTIR, FIR, THz, and Raman spectra provide detailed information on the structures and coordination of hydroxyl groups to metal ions in the metal-carbohydrate complexes. (C) 2012 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000310843700003 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48283]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Limin |
| 作者单位 | 1.Peking Univ, Sch Phys, Inst Heavy Ion Phys, State Key Lab Nucl Phys & Technol, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 3.Inner Mongolia Univ Technol, Coll Chem Engn, Hohhot 010051, Peoples R China 4.Capital Normal Univ, Dept Phys, Beijing 100037, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, Junhui,Hua, Xiaohui,Li, Weihong,et al. Sugar-metal ion interactions: the coordination behaviors of lanthanum with erythritol[J]. CARBOHYDRATE RESEARCH,2012,361:12-18. |
| APA | Xue, Junhui.,Hua, Xiaohui.,Li, Weihong.,Yang, Limin.,Xu, Yizhuang.,...&Wu, Jinguang.(2012).Sugar-metal ion interactions: the coordination behaviors of lanthanum with erythritol.CARBOHYDRATE RESEARCH,361,12-18. |
| MLA | Xue, Junhui,et al."Sugar-metal ion interactions: the coordination behaviors of lanthanum with erythritol".CARBOHYDRATE RESEARCH 361(2012):12-18. |
入库方式： OAI收割
来源：化学研究所
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